苯并双硫基[3,2-c]喹啉：16族元素的调谐电子和结构性质

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-11-29 DOI:10.1039/D4QO01921K

Christopher Hüßler, Martin C. Dietl, Matthias Scherr, Emma Butigan, Robin Heckershoff, Eric F. Lopes, Justin Kahle, Petra Krämer, Frank Rominger, Matthias Rudolph and A. Stephen K. Hashmi

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引用次数: 0

摘要

以硫、硒和碲为原料，通过亲核环化反应合成了硫取代π扩展吲哚咔唑，并进行Pictet-Spengler反应。这些组合的合成策略使得易于获得七环π扩展分子，在合成路线的各个阶段提供了广泛的模块化。共合成了26个新的七环类化合物。实验和理论研究了它们的光物理和结构性质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Benzobischalcogeno[3,2-c]quinolines: tuning electronic and structural properties with group 16 elements†

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Benzobischalcogeno[3,2-c]quinolines: tuning electronic and structural properties with group 16 elements†

Chalcogen-substituted π-extended indolocarbazoles were synthesized through a nucleophilic cyclization of tethered diynes with sulfur, selenium or tellurium sources, followed by a Pictet–Spengler reaction. These combined synthetic strategies enabled the facile access to heptacyclic π-extended molecules, offering a broad modularity at various stages of the synthesis route. In total, twenty-six novel heptacyclic compounds were synthesized. Their photophysical and structural properties were investigated experimentally as well as theoretically.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.