{"title":"绿色可持续合成用于信息加密的雏菊荧光碳点","authors":"Jing Hu, Shaogui Wu","doi":"10.1016/j.molstruc.2024.140794","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, we report a sustainable and eco-friendly synthesis of green fluorescent carbon dots (G-CDs) from crown daisy, a common vegetable, and o-phenylenediamine via a hydrothermal method. The synthesized G-CDs were comprehensively characterized using various spectroscopic techniques, revealing a maximum excitation wavelength of 436 nm and emission at 539 nm with a quantum yield of up to 14.5 % in ethanol. The optical properties was systematically investigated, demonstrating the excellent salt tolerance, pH stability, and photostability of the G-CDs. Notably, the G-CDs exhibited excitation-independent emissions behavior, indicating a single type of fluorescent emission center. The practical application of G-CDs as anti-counterfeiting ink was demonstrated by generating a clear QR code pattern under UV illumination, showcasing their potential for information encryption and anti-counterfeiting applications. This work not only provides a sustainable and cost-effective approach for G-CD synthesis but also highlights their promising prospects in optical anti-counterfeiting and information encryption domains.</div></div>","PeriodicalId":16414,"journal":{"name":"Journal of Molecular Structure","volume":"1324 ","pages":"Article 140794"},"PeriodicalIF":4.0000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green and sustainable synthesis of fluorescent carbon dots from crown daisy for information encryption application\",\"authors\":\"Jing Hu, Shaogui Wu\",\"doi\":\"10.1016/j.molstruc.2024.140794\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Herein, we report a sustainable and eco-friendly synthesis of green fluorescent carbon dots (G-CDs) from crown daisy, a common vegetable, and o-phenylenediamine via a hydrothermal method. The synthesized G-CDs were comprehensively characterized using various spectroscopic techniques, revealing a maximum excitation wavelength of 436 nm and emission at 539 nm with a quantum yield of up to 14.5 % in ethanol. The optical properties was systematically investigated, demonstrating the excellent salt tolerance, pH stability, and photostability of the G-CDs. Notably, the G-CDs exhibited excitation-independent emissions behavior, indicating a single type of fluorescent emission center. The practical application of G-CDs as anti-counterfeiting ink was demonstrated by generating a clear QR code pattern under UV illumination, showcasing their potential for information encryption and anti-counterfeiting applications. This work not only provides a sustainable and cost-effective approach for G-CD synthesis but also highlights their promising prospects in optical anti-counterfeiting and information encryption domains.</div></div>\",\"PeriodicalId\":16414,\"journal\":{\"name\":\"Journal of Molecular Structure\",\"volume\":\"1324 \",\"pages\":\"Article 140794\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-11-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Structure\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022286024033027\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Structure","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022286024033027","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Green and sustainable synthesis of fluorescent carbon dots from crown daisy for information encryption application
Herein, we report a sustainable and eco-friendly synthesis of green fluorescent carbon dots (G-CDs) from crown daisy, a common vegetable, and o-phenylenediamine via a hydrothermal method. The synthesized G-CDs were comprehensively characterized using various spectroscopic techniques, revealing a maximum excitation wavelength of 436 nm and emission at 539 nm with a quantum yield of up to 14.5 % in ethanol. The optical properties was systematically investigated, demonstrating the excellent salt tolerance, pH stability, and photostability of the G-CDs. Notably, the G-CDs exhibited excitation-independent emissions behavior, indicating a single type of fluorescent emission center. The practical application of G-CDs as anti-counterfeiting ink was demonstrated by generating a clear QR code pattern under UV illumination, showcasing their potential for information encryption and anti-counterfeiting applications. This work not only provides a sustainable and cost-effective approach for G-CD synthesis but also highlights their promising prospects in optical anti-counterfeiting and information encryption domains.
期刊介绍:
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