Trupti Kathrotia , Thomas Bierkandt , Nina Gaiser , Sandra Richter , Fabian Lindner , Sascha Jacobs , Clemens Naumann , Torsten Methling , Patrick Oßwald , Markus Köhler
{"title":"替代燃料的燃烧动力学,第 IV 部分:扩展反应机制 \"DLR 简明版\",纳入含氧组分","authors":"Trupti Kathrotia , Thomas Bierkandt , Nina Gaiser , Sandra Richter , Fabian Lindner , Sascha Jacobs , Clemens Naumann , Torsten Methling , Patrick Oßwald , Markus Köhler","doi":"10.1016/j.combustflame.2024.113841","DOIUrl":null,"url":null,"abstract":"<div><div>In our previous work on hydrocarbons (Kathrotia et al., Fuel 2021;302:120736) and jet fuels (Kathrotia et al., Fuel 2021;302:120737) the molecular fuel composition was shown to be an important aspect of understanding the fuel combustion chemistry and, more importantly, the emission behavior. In this extension, we elaborate our high-temperature jet fuel surrogate reaction mechanism (referred hereafter as DLR Concise) to include the chemical class of oxygenated hydrocarbons for transportation fuels. These oxygen containing species have been widely investigated in ground transportation fuels. With DLR Concise we aim for a flexible reaction model for alternative fuel surrogates; a single reaction model with the target application to both aviation- as well as transportation-fuels.</div><div>The main focus of this work is to describe the reaction kinetics of oxymethylene ethers (OME<sub>x</sub>, x = 0–5) in low to high temperatures. OMEs are promising alternative fuels that can be derived from a variety of sustainable sources. The absence or reduction of C-C bonds makes them attractive for the reduction of soot precursors and soot emissions. The reaction model of OMEs presented in this work is extensively validated against wide-ranging experiments both in-house and from literature. The main purpose of the DLR Concise is to provide a reaction mechanism with a large degree in flexibility to simulate various fuel surrogates (existing and new) and predict pollutants for the fuel assessment based on fuel molecular structure.</div><div>A comprehensive model validation as well as new in-house experimental data set on C<sub>1</sub>-C<sub>4</sub> alcohols and primary reference fuel (PRF90) measured in high-temperature flow reactor is available as supplemental material.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"271 ","pages":"Article 113841"},"PeriodicalIF":5.8000,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Combustion kinetics of alternative fuels, Part-IV: Extending reaction mechanism “DLR Concise” to include oxygenates components\",\"authors\":\"Trupti Kathrotia , Thomas Bierkandt , Nina Gaiser , Sandra Richter , Fabian Lindner , Sascha Jacobs , Clemens Naumann , Torsten Methling , Patrick Oßwald , Markus Köhler\",\"doi\":\"10.1016/j.combustflame.2024.113841\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In our previous work on hydrocarbons (Kathrotia et al., Fuel 2021;302:120736) and jet fuels (Kathrotia et al., Fuel 2021;302:120737) the molecular fuel composition was shown to be an important aspect of understanding the fuel combustion chemistry and, more importantly, the emission behavior. In this extension, we elaborate our high-temperature jet fuel surrogate reaction mechanism (referred hereafter as DLR Concise) to include the chemical class of oxygenated hydrocarbons for transportation fuels. These oxygen containing species have been widely investigated in ground transportation fuels. With DLR Concise we aim for a flexible reaction model for alternative fuel surrogates; a single reaction model with the target application to both aviation- as well as transportation-fuels.</div><div>The main focus of this work is to describe the reaction kinetics of oxymethylene ethers (OME<sub>x</sub>, x = 0–5) in low to high temperatures. OMEs are promising alternative fuels that can be derived from a variety of sustainable sources. The absence or reduction of C-C bonds makes them attractive for the reduction of soot precursors and soot emissions. The reaction model of OMEs presented in this work is extensively validated against wide-ranging experiments both in-house and from literature. The main purpose of the DLR Concise is to provide a reaction mechanism with a large degree in flexibility to simulate various fuel surrogates (existing and new) and predict pollutants for the fuel assessment based on fuel molecular structure.</div><div>A comprehensive model validation as well as new in-house experimental data set on C<sub>1</sub>-C<sub>4</sub> alcohols and primary reference fuel (PRF90) measured in high-temperature flow reactor is available as supplemental material.</div></div>\",\"PeriodicalId\":280,\"journal\":{\"name\":\"Combustion and Flame\",\"volume\":\"271 \",\"pages\":\"Article 113841\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Combustion and Flame\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010218024005509\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Combustion and Flame","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010218024005509","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Combustion kinetics of alternative fuels, Part-IV: Extending reaction mechanism “DLR Concise” to include oxygenates components
In our previous work on hydrocarbons (Kathrotia et al., Fuel 2021;302:120736) and jet fuels (Kathrotia et al., Fuel 2021;302:120737) the molecular fuel composition was shown to be an important aspect of understanding the fuel combustion chemistry and, more importantly, the emission behavior. In this extension, we elaborate our high-temperature jet fuel surrogate reaction mechanism (referred hereafter as DLR Concise) to include the chemical class of oxygenated hydrocarbons for transportation fuels. These oxygen containing species have been widely investigated in ground transportation fuels. With DLR Concise we aim for a flexible reaction model for alternative fuel surrogates; a single reaction model with the target application to both aviation- as well as transportation-fuels.
The main focus of this work is to describe the reaction kinetics of oxymethylene ethers (OMEx, x = 0–5) in low to high temperatures. OMEs are promising alternative fuels that can be derived from a variety of sustainable sources. The absence or reduction of C-C bonds makes them attractive for the reduction of soot precursors and soot emissions. The reaction model of OMEs presented in this work is extensively validated against wide-ranging experiments both in-house and from literature. The main purpose of the DLR Concise is to provide a reaction mechanism with a large degree in flexibility to simulate various fuel surrogates (existing and new) and predict pollutants for the fuel assessment based on fuel molecular structure.
A comprehensive model validation as well as new in-house experimental data set on C1-C4 alcohols and primary reference fuel (PRF90) measured in high-temperature flow reactor is available as supplemental material.
期刊介绍:
The mission of the journal is to publish high quality work from experimental, theoretical, and computational investigations on the fundamentals of combustion phenomena and closely allied matters. While submissions in all pertinent areas are welcomed, past and recent focus of the journal has been on:
Development and validation of reaction kinetics, reduction of reaction mechanisms and modeling of combustion systems, including:
Conventional, alternative and surrogate fuels;
Pollutants;
Particulate and aerosol formation and abatement;
Heterogeneous processes.
Experimental, theoretical, and computational studies of laminar and turbulent combustion phenomena, including:
Premixed and non-premixed flames;
Ignition and extinction phenomena;
Flame propagation;
Flame structure;
Instabilities and swirl;
Flame spread;
Multi-phase reactants.
Advances in diagnostic and computational methods in combustion, including:
Measurement and simulation of scalar and vector properties;
Novel techniques;
State-of-the art applications.
Fundamental investigations of combustion technologies and systems, including:
Internal combustion engines;
Gas turbines;
Small- and large-scale stationary combustion and power generation;
Catalytic combustion;
Combustion synthesis;
Combustion under extreme conditions;
New concepts.