铃木-宫浦交叉偶联反应中钯裂碱催化剂的最新研究进展:综述

IF 2.1 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Iman Hussein Hasan , Raed Muslim Mhaibes , Abdul Amir H. Kadhum , Hussein Ali Al-Bahrani , Ali Thoulfikar A. Imeer , Nihad A.M Al-Rashedi , Guang Shu
{"title":"铃木-宫浦交叉偶联反应中钯裂碱催化剂的最新研究进展:综述","authors":"Iman Hussein Hasan ,&nbsp;Raed Muslim Mhaibes ,&nbsp;Abdul Amir H. Kadhum ,&nbsp;Hussein Ali Al-Bahrani ,&nbsp;Ali Thoulfikar A. Imeer ,&nbsp;Nihad A.M Al-Rashedi ,&nbsp;Guang Shu","doi":"10.1016/j.jorganchem.2024.123444","DOIUrl":null,"url":null,"abstract":"<div><div>Carbon-carbon cross-coupling organic transformations are crucial in organic chemistry, but achieving them without a catalyst is challenging. Various catalysts based on complex have been developed to facilitate these reactions. Firstly, ligands based on phosphine were used, but their sensitive nature and toxic led researchers to turn to ligands based on Schiff base. These ligands are stable, simple to synthesize, and produce a variety of transition metal complexes. Ligands based on Schiff base are typically synthesized from the condensation reaction between carbonyl compounds and an amino group, and their complexes along with transition metal are widely used in different carbon–carbon cross-coupling organic transformations. In particular, palladium complexes, are well-known catalytic systems in carbon-carbon cross-coupling organic transformations such as the Suzuki-Miyaura cross-coupling organic transformations. This review focuses on the application of Pd Schiff base ligands in Suzuki-Miyaura reaction.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1024 ","pages":"Article 123444"},"PeriodicalIF":2.1000,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances on Pd schiff base catalysts in suzuki-miyaura cross-coupling reaction: A review\",\"authors\":\"Iman Hussein Hasan ,&nbsp;Raed Muslim Mhaibes ,&nbsp;Abdul Amir H. Kadhum ,&nbsp;Hussein Ali Al-Bahrani ,&nbsp;Ali Thoulfikar A. Imeer ,&nbsp;Nihad A.M Al-Rashedi ,&nbsp;Guang Shu\",\"doi\":\"10.1016/j.jorganchem.2024.123444\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carbon-carbon cross-coupling organic transformations are crucial in organic chemistry, but achieving them without a catalyst is challenging. Various catalysts based on complex have been developed to facilitate these reactions. Firstly, ligands based on phosphine were used, but their sensitive nature and toxic led researchers to turn to ligands based on Schiff base. These ligands are stable, simple to synthesize, and produce a variety of transition metal complexes. Ligands based on Schiff base are typically synthesized from the condensation reaction between carbonyl compounds and an amino group, and their complexes along with transition metal are widely used in different carbon–carbon cross-coupling organic transformations. In particular, palladium complexes, are well-known catalytic systems in carbon-carbon cross-coupling organic transformations such as the Suzuki-Miyaura cross-coupling organic transformations. This review focuses on the application of Pd Schiff base ligands in Suzuki-Miyaura reaction.</div></div>\",\"PeriodicalId\":374,\"journal\":{\"name\":\"Journal of Organometallic Chemistry\",\"volume\":\"1024 \",\"pages\":\"Article 123444\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-11-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022328X2400439X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022328X2400439X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要

碳-碳交叉偶联有机转化在有机化学中至关重要,但在没有催化剂的情况下实现这些转化具有挑战性。为了促进这些反应,人们开发了各种基于络合物的催化剂。首先,人们使用了基于膦的配体,但由于其敏感性和毒性,研究人员转而使用基于席夫碱的配体。这些配体稳定、合成简单,并能产生各种过渡金属配合物。基于席夫碱的配体通常由羰基化合物与氨基的缩合反应合成,其配合物与过渡金属一起被广泛应用于不同的碳-碳交叉偶联有机转化中。尤其是钯配合物,是碳碳交叉偶联有机转化(如铃木-宫浦交叉偶联有机转化)中著名的催化体系。本综述重点介绍钯希夫碱配体在铃木-宫浦反应中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent advances on Pd schiff base catalysts in suzuki-miyaura cross-coupling reaction: A review

Recent advances on Pd schiff base catalysts in suzuki-miyaura cross-coupling reaction: A review
Carbon-carbon cross-coupling organic transformations are crucial in organic chemistry, but achieving them without a catalyst is challenging. Various catalysts based on complex have been developed to facilitate these reactions. Firstly, ligands based on phosphine were used, but their sensitive nature and toxic led researchers to turn to ligands based on Schiff base. These ligands are stable, simple to synthesize, and produce a variety of transition metal complexes. Ligands based on Schiff base are typically synthesized from the condensation reaction between carbonyl compounds and an amino group, and their complexes along with transition metal are widely used in different carbon–carbon cross-coupling organic transformations. In particular, palladium complexes, are well-known catalytic systems in carbon-carbon cross-coupling organic transformations such as the Suzuki-Miyaura cross-coupling organic transformations. This review focuses on the application of Pd Schiff base ligands in Suzuki-Miyaura reaction.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Organometallic Chemistry
Journal of Organometallic Chemistry 化学-无机化学与核化学
CiteScore
4.40
自引率
8.70%
发文量
221
审稿时长
36 days
期刊介绍: The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信