{"title":"用于去除阴离子和阳离子染料的西米树皮(Metroxylon sagu)EDTA 改性纤维素","authors":"Syiffa Fauzia, Fitri Yuliani, Suherman Suherman, Shafa Kamasinta","doi":"10.1002/ep.14489","DOIUrl":null,"url":null,"abstract":"<p>The present research employed ethylenediaminetetraacetic (EDTA) modified cellulose to remove basic violet 10 (BV10) and reactive orange 16 (RO16) dyes. The cellulose was obtained from sago bark which was solid waste of sago starch industries. Sago bark contains 56.86% cellulose so that it can provide significant amount of active site. The optimum condition was examined using batch method investigating some parameters including pH, initial dye concentration, contact time, and thermodynamics. The adsorption capacity of cellulose (Cell) itself was also investigated for the comparison. The characterization of adsorbent showed the presence of ester bond, amine groups and escalating of surface area and pores after EDTA modification. The adsorption capacity of EDTA-modified cellulose (Cell-EDTA) was 73.53 mg/g for BV10 and 22.42 mg/g for RO16. The adsorption of both dyes onto Cell-EDTA followed Langmuir isotherm model and pseudo-second-order kinetic model. Thermodynamic parameters indicated that the adsorption process was spontaneous, endothermic and feasible. Desorption studies proved that NaOH was an effective desorbing agent of BV10 and RO16. Based on research, Cell-EDTA was more favorable in cationic dye, basic violet 10 than anionic dye, reactive orange 16.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"43 6","pages":""},"PeriodicalIF":2.1000,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"EDTA-modified cellulose from sago bark (Metroxylon sagu) for anionic and cationic dyes removal\",\"authors\":\"Syiffa Fauzia, Fitri Yuliani, Suherman Suherman, Shafa Kamasinta\",\"doi\":\"10.1002/ep.14489\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The present research employed ethylenediaminetetraacetic (EDTA) modified cellulose to remove basic violet 10 (BV10) and reactive orange 16 (RO16) dyes. The cellulose was obtained from sago bark which was solid waste of sago starch industries. Sago bark contains 56.86% cellulose so that it can provide significant amount of active site. The optimum condition was examined using batch method investigating some parameters including pH, initial dye concentration, contact time, and thermodynamics. The adsorption capacity of cellulose (Cell) itself was also investigated for the comparison. The characterization of adsorbent showed the presence of ester bond, amine groups and escalating of surface area and pores after EDTA modification. The adsorption capacity of EDTA-modified cellulose (Cell-EDTA) was 73.53 mg/g for BV10 and 22.42 mg/g for RO16. The adsorption of both dyes onto Cell-EDTA followed Langmuir isotherm model and pseudo-second-order kinetic model. Thermodynamic parameters indicated that the adsorption process was spontaneous, endothermic and feasible. Desorption studies proved that NaOH was an effective desorbing agent of BV10 and RO16. Based on research, Cell-EDTA was more favorable in cationic dye, basic violet 10 than anionic dye, reactive orange 16.</p>\",\"PeriodicalId\":11701,\"journal\":{\"name\":\"Environmental Progress & Sustainable Energy\",\"volume\":\"43 6\",\"pages\":\"\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-10-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Progress & Sustainable Energy\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ep.14489\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Progress & Sustainable Energy","FirstCategoryId":"93","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ep.14489","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
EDTA-modified cellulose from sago bark (Metroxylon sagu) for anionic and cationic dyes removal
The present research employed ethylenediaminetetraacetic (EDTA) modified cellulose to remove basic violet 10 (BV10) and reactive orange 16 (RO16) dyes. The cellulose was obtained from sago bark which was solid waste of sago starch industries. Sago bark contains 56.86% cellulose so that it can provide significant amount of active site. The optimum condition was examined using batch method investigating some parameters including pH, initial dye concentration, contact time, and thermodynamics. The adsorption capacity of cellulose (Cell) itself was also investigated for the comparison. The characterization of adsorbent showed the presence of ester bond, amine groups and escalating of surface area and pores after EDTA modification. The adsorption capacity of EDTA-modified cellulose (Cell-EDTA) was 73.53 mg/g for BV10 and 22.42 mg/g for RO16. The adsorption of both dyes onto Cell-EDTA followed Langmuir isotherm model and pseudo-second-order kinetic model. Thermodynamic parameters indicated that the adsorption process was spontaneous, endothermic and feasible. Desorption studies proved that NaOH was an effective desorbing agent of BV10 and RO16. Based on research, Cell-EDTA was more favorable in cationic dye, basic violet 10 than anionic dye, reactive orange 16.
期刊介绍:
Environmental Progress , a quarterly publication of the American Institute of Chemical Engineers, reports on critical issues like remediation and treatment of solid or aqueous wastes, air pollution, sustainability, and sustainable energy. Each issue helps chemical engineers (and those in related fields) stay on top of technological advances in all areas associated with the environment through feature articles, updates, book and software reviews, and editorials.