利用造纸业废料作为合成生物柴油的异相基础催化剂

IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL
Sultana Parveen Ahmed, Sudhamoyee Kataky, Riku Dutta, Ashim Jyoti Thakur, Swapan Kumar Dolui
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引用次数: 0

摘要

为了满足当今世界对替代生物燃料的迫切需求,必须降低生物柴油的生产成本。因此,本研究利用印度阿萨姆邦当地造纸业产生的富含 CaCO3 的工业废料,合成用于合成生物柴油的异相催化剂。收集的石灰污泥废料在 800°C 煅烧 3 小时后产生富含 CaO 的催化剂,然后用于棉籽油的酯交换反应。优化后的反应条件为:催化剂浓度为 5 wt%,油与甲醇的摩尔比为 1:12,温度为 65°C,反应时间为 3 小时。对催化剂的重复使用性进行了评估,最多可重复使用四次。此外,还使用傅立叶变换红外光谱(FTIR)、粉末 X 射线衍射(p-XRD)、扫描电子显微镜(SEM)、能量色散 X 射线分析(EDX)和布鲁瑙尔-艾美特-泰勒(BET)技术对制备的催化剂进行了表征,并使用哈米特指标测量了其碱性。此外,还利用 1H-核磁共振(NMR)、13C-核磁共振(13C-NMR)、气相色谱-质谱(GC-MS)和傅立叶变换红外(FTIR)技术对生物柴油进行了表征。生物柴油产率达到 98.03%,CSO 的酯交换反应生成的生物柴油质量也符合 EN 14214 和 ASTM D 6751 标准。因此,我们的研究强调了造纸工业废料在生物柴油生产中的可持续性和未来工业应用的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Utilization of waste from paper industry as a heterogeneous base catalyst for the synthesis of biodiesel

To meet the pressing demand for alternative biofuel in the contemporary world, the production cost of biodiesel has to be decreased. Hence, this work addresses the usage of CaCO3-rich industrial waste produced in a local paper industry in Assam, India for the synthesis of a heterogeneous catalyst for biodiesel synthesis. The collected lime sludge waste was subjected to calcination at 800°C for 3 h producing a CaO-rich catalyst which was then employed in the transesterification of cottonseed oil. The optimized reaction conditions obtained were 5 wt% catalyst concentration, oil to methanol molar ratio of 1:12 at 65°C temperature, and 3 h of reaction time. The catalyst's reusability was evaluated up to four cycles. Besides, the prepared catalyst has been characterized using Fourier transfer infrared spectroscopy (FTIR), powder X-ray Diffraction (p-XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray analysis (EDX), and Brunauer–Emmett–Teller (BET) techniques and its basicity was measured using Hammett indicators. Moreover, the biodiesel obtained was characterized with 1H-nuclear magnetic resonance (NMR), 13C-NMR, Gas Chromatography- Mass Spectrometry (GC–MS), and FTIR techniques. A biodiesel yield of 98.03% was achieved and the quality of biodiesel formed during the transesterification of CSO also conforms to EN 14214 and ASTM D 6751 standards. Thus, our study highlights the sustainability and the potential for future industrial application of paper industrial waste in the production of biodiesel.

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来源期刊
Environmental Progress & Sustainable Energy
Environmental Progress & Sustainable Energy 环境科学-工程:化工
CiteScore
5.00
自引率
3.60%
发文量
231
审稿时长
4.3 months
期刊介绍: Environmental Progress , a quarterly publication of the American Institute of Chemical Engineers, reports on critical issues like remediation and treatment of solid or aqueous wastes, air pollution, sustainability, and sustainable energy. Each issue helps chemical engineers (and those in related fields) stay on top of technological advances in all areas associated with the environment through feature articles, updates, book and software reviews, and editorials.
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