光催化裂解与胺及其衍生物有关的 C-C 和 C-N 键的最新进展

IF 4.6 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-11-22 DOI:10.1039/d4qo02038c

Qibo Ni, Yan Zhou, Lang Chen, Yunkui Liu

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引用次数: 0

摘要

无处不在的胺及其衍生物中 C-C 和 C-N 键的裂解是构建有价值有机分子的重要而有用的方法。与传统的热反应方案相比，可见光驱动的光催化 C-C 和 C-N 键裂解策略具有反应条件温和、选择性独特、操作对环境无害等特点，因此近年来备受关注。本综述总结了最近在可见光介导的光催化裂解与胺及其衍生物相关的 C-C 和 C-N 键方面取得的进展。综述最后指出了这一领域的局限性和挑战，并展望了这一领域未来的研究方向。

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Recent advances in the photocatalytic cleavage of C–C and C–N bonds associated with amines and their derivatives

The cleavage of C-C and C-N bonds in ubiquitous amines and their derivatives serves as an important and useful protocol for the construction of valuable organic molecules. Recently, the visible-light-driven photocatalytic strategy for the C-C and C-N bond scissions has received much attention because such strategy has characteristic advantages of mild reaction conditions, unique selectivities and environmentally benign operations in comparison with the traditional thermal reaction protocols. In this review, the recent advances in the visible-light-mediated photocatalytic cleavage of C-C and C-N bond associated with amines and their derivatives are summarized. At the end of this review, the limitations and challenges in this field are pointed out, and the future research direction of this field is also prospected.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.