热力学第二定律与分散系统的表面特性

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2024-11-18 DOI:10.1134/S0036024424702078

Yu. K. Tovbin

{"title":"热力学第二定律与分散系统的表面特性","authors":"Yu. K. Tovbin","doi":"10.1134/S0036024424702078","DOIUrl":null,"url":null,"abstract":"<p>An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"98 12","pages":"2823 - 2827"},"PeriodicalIF":0.7000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Second Law of Thermodynamics and the Surface Characteristics of Dispersed Systems\",\"authors\":\"Yu. K. Tovbin\",\"doi\":\"10.1134/S0036024424702078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"98 12\",\"pages\":\"2823 - 2827\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-11-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024424702078\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424702078","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

对文献的分析表明，分散系统的所有表面特征（表面张力、接触角、分离压力和小系统的特性）在热力学定义上都存在模糊性。克劳修斯热力学第二定律需要关于动量、能量和质量传递过程弛豫期的额外实验数据，该定律用于消除这种模糊性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

The Second Law of Thermodynamics and the Surface Characteristics of Dispersed Systems

An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.