封面：光化学与热酸催化的大麻萜醇（CBG）环化：意想不到的选择性（ChemPhotoChem 11/2024）

IF 3 4区化学 Q3 CHEMISTRY, PHYSICAL

ChemPhotoChem Pub Date : 2024-11-13 DOI:10.1002/cptc.202481101

Arianna Bini, Prof. Mariella Mella, Prof. Daniele Merli, Prof. Stefano Protti

{"title":"封面：光化学与热酸催化的大麻萜醇（CBG）环化：意想不到的选择性（ChemPhotoChem 11/2024）","authors":"Arianna Bini, Prof. Mariella Mella, Prof. Daniele Merli, Prof. Stefano Protti","doi":"10.1002/cptc.202481101","DOIUrl":null,"url":null,"abstract":"The Front Cover highlights investigations of the reactivity of Cannabigerol (CBG) in organic solvents under both photochemical and acid catalyzed conditions, pointing out the key role of the photoexcited CBG* in the selective formation of a 2,2-disubstituted-chromane derivative (green path). On the other hand, in the presence of Brønsted-Lowry acids, two tertiary carbocations are competitively generated (I+, II+, orange and blue paths). Finally, when performing the reaction in toluene in the presence of BF3*OEt2, a Friedel Crafts-like alkylation of the solvent was noticed (purple paths). More information can be found in the Research Article by Daniele Merli, Stefano Protti, and co-workers (DOI: 10.1002/cptc.202400157).\n <figure>\n <div><picture>\n <source></source></picture>\n </div>\n </figure>\n ","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"8 11","pages":""},"PeriodicalIF":3.0000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202481101","citationCount":"0","resultStr":"{\"title\":\"Front Cover: Photochemical Vs Thermal Acid Catalysed Cyclization of Cannabigerol (CBG): An Unexpected Selectivity (ChemPhotoChem 11/2024)\",\"authors\":\"Arianna Bini, Prof. Mariella Mella, Prof. Daniele Merli, Prof. Stefano Protti\",\"doi\":\"10.1002/cptc.202481101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Front Cover highlights investigations of the reactivity of Cannabigerol (CBG) in organic solvents under both photochemical and acid catalyzed conditions, pointing out the key role of the photoexcited CBG* in the selective formation of a 2,2-disubstituted-chromane derivative (green path). On the other hand, in the presence of Brønsted-Lowry acids, two tertiary carbocations are competitively generated (I+, II+, orange and blue paths). Finally, when performing the reaction in toluene in the presence of BF3*OEt2, a Friedel Crafts-like alkylation of the solvent was noticed (purple paths). More information can be found in the Research Article by Daniele Merli, Stefano Protti, and co-workers (DOI: 10.1002/cptc.202400157).\\n <figure>\\n <div><picture>\\n <source></source></picture>\\n </div>\\n </figure>\\n \",\"PeriodicalId\":10108,\"journal\":{\"name\":\"ChemPhotoChem\",\"volume\":\"8 11\",\"pages\":\"\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202481101\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemPhotoChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cptc.202481101\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemPhotoChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cptc.202481101","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

封面重点介绍了在光化学和酸催化条件下，大麻萜醇（CBG）在有机溶剂中的反应性研究，指出了光激发的 CBG* 在选择性生成 2,2-二取代-铬烷衍生物（绿色路径）中的关键作用。另一方面，在布氏-洛氏酸存在的条件下，两个叔碳基竞争性地生成（I+、II+，橙色和蓝色路径）。最后，在有 BF3*OEt2 存在的甲苯中进行反应时，发现溶剂发生了类似 Friedel Crafts 的烷基化反应（紫色路径）。更多信息，请参阅 Daniele Merli、Stefano Protti 及合作者的研究文章（DOI: 10.1002/cptc.202400157）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Front Cover: Photochemical Vs Thermal Acid Catalysed Cyclization of Cannabigerol (CBG): An Unexpected Selectivity (ChemPhotoChem 11/2024)

查看原文本刊更多论文

Front Cover: Photochemical Vs Thermal Acid Catalysed Cyclization of Cannabigerol (CBG): An Unexpected Selectivity (ChemPhotoChem 11/2024)

The Front Cover highlights investigations of the reactivity of Cannabigerol (CBG) in organic solvents under both photochemical and acid catalyzed conditions, pointing out the key role of the photoexcited CBG* in the selective formation of a 2,2-disubstituted-chromane derivative (green path). On the other hand, in the presence of Brønsted-Lowry acids, two tertiary carbocations are competitively generated (I⁺, II⁺, orange and blue paths). Finally, when performing the reaction in toluene in the presence of BF₃*OEt₂, a Friedel Crafts-like alkylation of the solvent was noticed (purple paths). More information can be found in the Research Article by Daniele Merli, Stefano Protti, and co-workers (DOI: 10.1002/cptc.202400157).

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

ChemPhotoChem Chemistry-Physical and Theoretical Chemistry

CiteScore

5.80

自引率

5.40%

发文量

165

期刊介绍： Light plays a crucial role in natural processes and leads to exciting phenomena in molecules and materials. ChemPhotoChem welcomes exceptional international research in the entire scope of pure and applied photochemistry, photobiology, and photophysics. Our thorough editorial practices aid us in publishing authoritative research fast. We support the photochemistry community to be a leading light in science. We understand the huge pressures the scientific community is facing every day and we want to support you. Chemistry Europe is an association of 16 chemical societies from 15 European countries. Run by chemists, for chemists—we evaluate, publish, disseminate, and amplify the scientific excellence of chemistry researchers from around the globe.