{"title":"构建用于高效降解有机污染物的 Pr/CDs/SSS/PbO2 复合电极†。","authors":"Hui Li, Guiyun Yi, Yuanfeng Wu, Xikui Wang, Baolin Xing and Yulong Zhang","doi":"10.1039/D4CE00791C","DOIUrl":null,"url":null,"abstract":"<p >In this study, a Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode with good electrocatalytic activity and superior stability was successfully prepared by an electrodeposition process. XRD results showed that the doping of the Pr element inhibited the PbO<small><sub>2</sub></small> crystal growth, resulting in the complete disappearance of the α-PbO<small><sub>2</sub></small> diffraction peaks. Compared with the pure PbO<small><sub>2</sub></small> electrode, the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode possesses a smaller grain size and a more compact electrode surface structure. In addition, the results of XRD and XPS confirmed that Pr<small><sup>3+</sup></small> and Pr<small><sup>4+</sup></small> existed simultaneously in the electrode, which increased the oxygen precipitation over potential (1.96 V) and reduced the interfacial resistance (5.01 Ω) of the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode. Significantly, the prepared Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode showed the highest catalytic activity when the electrode was prepared in 5 mmol L<small><sup>−1</sup></small> of Pr-containing solution, and the degradation of MB by the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode was 98.2% after 180 min of degradation under the conditions: 50 mg L<small><sup>−1</sup></small> of MB, pH = 5, and 30 mA cm<small><sup>−2</sup></small> of current density. The removal rate of TOC was 58%, which was much higher than that of the pure PbO<small><sub>2</sub></small> electrode (3.44%). In general, the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode can be considered an efficient and low-cost anode material for the electrochemical treatment of organic wastewater.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 45","pages":" 6438-6447"},"PeriodicalIF":2.6000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of a Pr/CDs/SSS/PbO2 composite electrode for highly efficient degradation of organic pollutants†\",\"authors\":\"Hui Li, Guiyun Yi, Yuanfeng Wu, Xikui Wang, Baolin Xing and Yulong Zhang\",\"doi\":\"10.1039/D4CE00791C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In this study, a Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode with good electrocatalytic activity and superior stability was successfully prepared by an electrodeposition process. XRD results showed that the doping of the Pr element inhibited the PbO<small><sub>2</sub></small> crystal growth, resulting in the complete disappearance of the α-PbO<small><sub>2</sub></small> diffraction peaks. Compared with the pure PbO<small><sub>2</sub></small> electrode, the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode possesses a smaller grain size and a more compact electrode surface structure. In addition, the results of XRD and XPS confirmed that Pr<small><sup>3+</sup></small> and Pr<small><sup>4+</sup></small> existed simultaneously in the electrode, which increased the oxygen precipitation over potential (1.96 V) and reduced the interfacial resistance (5.01 Ω) of the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode. Significantly, the prepared Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode showed the highest catalytic activity when the electrode was prepared in 5 mmol L<small><sup>−1</sup></small> of Pr-containing solution, and the degradation of MB by the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode was 98.2% after 180 min of degradation under the conditions: 50 mg L<small><sup>−1</sup></small> of MB, pH = 5, and 30 mA cm<small><sup>−2</sup></small> of current density. The removal rate of TOC was 58%, which was much higher than that of the pure PbO<small><sub>2</sub></small> electrode (3.44%). In general, the Pr/CDs/SSS/PbO<small><sub>2</sub></small> electrode can be considered an efficient and low-cost anode material for the electrochemical treatment of organic wastewater.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 45\",\"pages\":\" 6438-6447\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00791c\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00791c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Construction of a Pr/CDs/SSS/PbO2 composite electrode for highly efficient degradation of organic pollutants†
In this study, a Pr/CDs/SSS/PbO2 electrode with good electrocatalytic activity and superior stability was successfully prepared by an electrodeposition process. XRD results showed that the doping of the Pr element inhibited the PbO2 crystal growth, resulting in the complete disappearance of the α-PbO2 diffraction peaks. Compared with the pure PbO2 electrode, the Pr/CDs/SSS/PbO2 electrode possesses a smaller grain size and a more compact electrode surface structure. In addition, the results of XRD and XPS confirmed that Pr3+ and Pr4+ existed simultaneously in the electrode, which increased the oxygen precipitation over potential (1.96 V) and reduced the interfacial resistance (5.01 Ω) of the Pr/CDs/SSS/PbO2 electrode. Significantly, the prepared Pr/CDs/SSS/PbO2 electrode showed the highest catalytic activity when the electrode was prepared in 5 mmol L−1 of Pr-containing solution, and the degradation of MB by the Pr/CDs/SSS/PbO2 electrode was 98.2% after 180 min of degradation under the conditions: 50 mg L−1 of MB, pH = 5, and 30 mA cm−2 of current density. The removal rate of TOC was 58%, which was much higher than that of the pure PbO2 electrode (3.44%). In general, the Pr/CDs/SSS/PbO2 electrode can be considered an efficient and low-cost anode material for the electrochemical treatment of organic wastewater.