1673 K 和 1873 K 下 Gd2O3-Nd2O3-ZrO2 系统的相关系

IF 1.9 3区材料科学 Q4 CHEMISTRY, PHYSICAL

Calphad-computer Coupling of Phase Diagrams and Thermochemistry Pub Date : 2024-11-13 DOI:10.1016/j.calphad.2024.102767

Kai Xu, Taowen Zheng, Xuezhen Che, Liumei Su, Dandan Huang

{"title":"1673 K 和 1873 K 下 Gd2O3-Nd2O3-ZrO2 系统的相关系","authors":"Kai Xu, Taowen Zheng, Xuezhen Che, Liumei Su, Dandan Huang","doi":"10.1016/j.calphad.2024.102767","DOIUrl":null,"url":null,"abstract":"<div><div>The phase relationship in the Gd2O3-Nd2O3-ZrO2 system at 1673 K and 1873 K was investigated by X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Samples with different compositions were annealed in air at temperatures of 1673 K and 1873 K after preparation. The isothermal section of the Gd2O3-Nd2O3-ZrO2 ternary system has been developed. No ternary compound was found at 1673 K and 1873 K. There exist fields of solid solution based on cubic (C) and monoclinic (B) modifications of Gd2O3, tetragonal (T) and cubic modifications of ZrO2, A-Nd2O3, and pyrochlore-type Nd2Zr2O7 phase.</div></div>","PeriodicalId":9436,"journal":{"name":"Calphad-computer Coupling of Phase Diagrams and Thermochemistry","volume":"87 ","pages":"Article 102767"},"PeriodicalIF":1.9000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Phase relationship in Gd2O3-Nd2O3-ZrO2 system at 1673 K and 1873 K\",\"authors\":\"Kai Xu, Taowen Zheng, Xuezhen Che, Liumei Su, Dandan Huang\",\"doi\":\"10.1016/j.calphad.2024.102767\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The phase relationship in the Gd2O3-Nd2O3-ZrO2 system at 1673 K and 1873 K was investigated by X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Samples with different compositions were annealed in air at temperatures of 1673 K and 1873 K after preparation. The isothermal section of the Gd2O3-Nd2O3-ZrO2 ternary system has been developed. No ternary compound was found at 1673 K and 1873 K. There exist fields of solid solution based on cubic (C) and monoclinic (B) modifications of Gd2O3, tetragonal (T) and cubic modifications of ZrO2, A-Nd2O3, and pyrochlore-type Nd2Zr2O7 phase.</div></div>\",\"PeriodicalId\":9436,\"journal\":{\"name\":\"Calphad-computer Coupling of Phase Diagrams and Thermochemistry\",\"volume\":\"87 \",\"pages\":\"Article 102767\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Calphad-computer Coupling of Phase Diagrams and Thermochemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0364591624001093\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Calphad-computer Coupling of Phase Diagrams and Thermochemistry","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0364591624001093","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

通过 X 射线衍射、扫描电子显微镜和电子探针显微分析，研究了 1673 K 和 1873 K 下 Gd2O3-Nd2O3-ZrO2 系统的相关系。不同成分的样品在制备后分别在 1673 K 和 1873 K 的温度下进行空气退火。开发出了 Gd2O3-Nd2O3-ZrO2 三元体系的等温段。Gd2O3 的立方（C）和单斜（B）、ZrO2 的四方（T）和立方、A-Nd2O3 和火成岩型 Nd2Zr2O7 相都存在固溶体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Phase relationship in Gd2O3-Nd2O3-ZrO2 system at 1673 K and 1873 K

The phase relationship in the Gd₂O₃-Nd₂O₃-ZrO₂ system at 1673 K and 1873 K was investigated by X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Samples with different compositions were annealed in air at temperatures of 1673 K and 1873 K after preparation. The isothermal section of the Gd₂O₃-Nd₂O₃-ZrO₂ ternary system has been developed. No ternary compound was found at 1673 K and 1873 K. There exist fields of solid solution based on cubic (C) and monoclinic (B) modifications of Gd₂O₃, tetragonal (T) and cubic modifications of ZrO₂, A-Nd₂O₃, and pyrochlore-type Nd₂Zr₂O₇ phase.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Calphad-computer Coupling of Phase Diagrams and Thermochemistry 化学-热力学

CiteScore

4.00

自引率

16.70%

发文量

审稿时长

2.5 months

期刊介绍： The design of industrial processes requires reliable thermodynamic data. CALPHAD (Computer Coupling of Phase Diagrams and Thermochemistry) aims to promote computational thermodynamics through development of models to represent thermodynamic properties for various phases which permit prediction of properties of multicomponent systems from those of binary and ternary subsystems, critical assessment of data and their incorporation into self-consistent databases, development of software to optimize and derive thermodynamic parameters and the development and use of databanks for calculations to improve understanding of various industrial and technological processes. This work is disseminated through the CALPHAD journal and its annual conference.