反芳香族金属杂环戊三烯络合物

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-11-04 DOI:10.1021/jacs.4c1414110.1021/jacs.4c14141

Bingjie Fu, Yarong Wang, Yue Zhao, Yang Li*, Wenfeng Jiang* and Wei Bai*,

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引用次数: 0

摘要

金属环戊三烯是一种常见而重要的五元金属环，目前还没有关于金属环戊三烯（反）芳香性的报道。这项研究提出了锇顺式二碳化络合物的新合成方法，并将其氧化为锇杂环戊三烯。实验和理论研究表明，锇杂环戊三烯单元是反芳香族的。这一发现为发现反芳香族物种提供了新的视角。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Antiaromatic Metallacyclopentatriene Complexes

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Antiaromatic Metallacyclopentatriene Complexes

There is no report on the (anti)aromaticity of metallacyclopentatrienes, one kind of common and important five-membered metallacycles. This work presents the novel synthesis of osmium cis-biscarbene complexes and their oxidation to osmacyclopentatrienes. The osmacyclopentatriene unit is antiaromatic, as revealed by experimental and theoretical studies. This finding provides new insight into the discovery of antiaromatic species.

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.