用简单的溶胶-凝胶法制备稳定的超疏水涂层

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL
K. K. Shen, G. F. Jin, X. M. Lv, Y. Z. Huang, Y. Jia, M. N. Gao
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引用次数: 0

摘要

众所周知,超疏水性材料具有广阔的应用前景。然而,许多超疏水涂层的制备方法过于复杂或稳定性差,限制了超疏水材料的实际应用。本文通过简单的溶胶-凝胶法在织物表面制备了一种稳定耐用的超疏涂层。该涂层的水接触角和植物油接触角分别为 160.5 ± 0.8° 和 154.8 ± 2.6°。具体来说,该超疏水涂层是通过简单的溶胶-凝胶法在织物表面接枝纳米二氧化硅,然后接枝 1H,1H,2H,2H-全氟癸基三甲氧基硅烷(FAS-17)作为疏水改性剂制备而成的。经过各种化学和机械稳定性测试,包括浓氨溶液浸泡、饱和氢氧化钠溶液浸泡、浓盐溶液浸泡和搅拌下的四氢呋喃浸泡,涂层仍能保持疏水性。该涂层还具有优异的透气性,有望在特殊保护领域大显身手。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Preparation of a Stable Super-Amphiphobic Coating via a Simple Sol–Gel Method

Preparation of a Stable Super-Amphiphobic Coating via a Simple Sol–Gel Method

It is well known that super-hydrophobic materials have a wide application prospect. However, many methods for preparing super-amphiphobic coatings are too complicated or have poor stability, which limits the practical application of super-amphiphobic materials. In this paper, a stable and durable super-amphiphobic coating is prepared on the fabric surface via a simple sol-gel method. The water and vegetable oil contact angles of this coating are 160.5 ± 0.8° and 154.8 ± 2.6°, respectively. Specifically, the super-amphiphobic coating is prepared by grafting nano-silica on the surface of the fabric by a simple sol-gel method, and then grafted 1H, 1H,2H,2H-perfluorodecyltrimethoxysilane (FAS-17) as a hydrophobic modifier. After various chemical and mechanical stability tests, including concentrated ammonia solution soaking, saturated sodium hydroxide solution soaking, concentrated salt solution soaking, and THF soaking with stirring, the coating still maintains hydrophobicity. And the coating has excellent air permeability, which is expected to have great potential in the field of special protection.

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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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