S. A. Kurnosenko, O. I. Silyukov, I. A. Rodionov, I. A. Minich, A. I. Ustinova, I. A. Zvereva
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Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products
In conditions of depletion of mineral reserves, plant biomass is considered a renewable natural resource that can be photocatalytically processed to produce energy-intensive and environmentally friendly hydrogen fuel. In this regard, the present article focuses on the improvement of photocatalytic activity of the layered perovskite-structured niobate HCa2Nb3O10 in the reactions of hydrogen production from aqueous solutions of typical plant biomass components, glucose and xylose, via its exfoliation into nanosheets followed by their reassembly and modification with a Pt cocatalyst. The reassembled compound obtained was shown to outperform in the activity the initial niobate and reference photocatalyst TiO2 P25 Degussa up to 6.3 and 5.3 times, respectively, providing a hydrogen production rate up to 24.2 mmol h−1g−1 and apparent quantum efficiency up to 10% in the mid-near ultraviolet range.
期刊介绍:
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.