{"title":"多孔三维铜-MOF:制备及在超级电容器、低温储氢和气体分离中的应用","authors":"Yaqing Zhang, Yujuan Zhang, Tuoping Hu","doi":"10.1016/j.ica.2024.122414","DOIUrl":null,"url":null,"abstract":"<div><div>Due to its unique porosity, metal–organic frameworks (MOFs) have great application prospects in the fields of gas adsorption and separation. However, the synthesis of multi-functional MOFs is still a great challenge. Herein, a multi-functional Cu-MOF of {[Cu<sub>2</sub>(TPTA)(H<sub>2</sub>O)<sub>2</sub>]·2DMF·NMP·4H<sub>2</sub>O}n with a porosity of 62.0 % was designed and synthesized. The H<sub>2</sub> adsorption amount of Cu-MOF is about 289.2 cm<sup>3</sup> g<sup>−1</sup> at 77 K and 1 bar. Meanwhile, the selectivity adsorption of Cu-MOF towards CO<sub>2</sub> over CH<sub>4</sub> (V:V = 0.5:0.5), CO<sub>2</sub>/N<sub>2</sub> (V:V = 0.5:0.5) and CO<sub>2</sub>/H<sub>2</sub> (V:V = 0.5:0.5) is 95.1, 139.2 and 147.5, respectively, which is 1.5 times higher than the previously reported Cu-MOFs. The Cu-MOF@NF//AC asymmetric supercapacitor demonstrates high specific capacitance (53.4 F g<sup>−1</sup>) and stability (90.3 % after 2000 cycles). Furthermore, this work presents a novel approach to design multifunctional materials with low temperature hydrogen storage, gas separation and energy storage properties.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"575 ","pages":"Article 122414"},"PeriodicalIF":2.7000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A porous three-dimensional Cu-MOF: Preparation and application in supercapacitors, low temperature hydrogen storage and gas separation\",\"authors\":\"Yaqing Zhang, Yujuan Zhang, Tuoping Hu\",\"doi\":\"10.1016/j.ica.2024.122414\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Due to its unique porosity, metal–organic frameworks (MOFs) have great application prospects in the fields of gas adsorption and separation. However, the synthesis of multi-functional MOFs is still a great challenge. Herein, a multi-functional Cu-MOF of {[Cu<sub>2</sub>(TPTA)(H<sub>2</sub>O)<sub>2</sub>]·2DMF·NMP·4H<sub>2</sub>O}n with a porosity of 62.0 % was designed and synthesized. The H<sub>2</sub> adsorption amount of Cu-MOF is about 289.2 cm<sup>3</sup> g<sup>−1</sup> at 77 K and 1 bar. Meanwhile, the selectivity adsorption of Cu-MOF towards CO<sub>2</sub> over CH<sub>4</sub> (V:V = 0.5:0.5), CO<sub>2</sub>/N<sub>2</sub> (V:V = 0.5:0.5) and CO<sub>2</sub>/H<sub>2</sub> (V:V = 0.5:0.5) is 95.1, 139.2 and 147.5, respectively, which is 1.5 times higher than the previously reported Cu-MOFs. The Cu-MOF@NF//AC asymmetric supercapacitor demonstrates high specific capacitance (53.4 F g<sup>−1</sup>) and stability (90.3 % after 2000 cycles). Furthermore, this work presents a novel approach to design multifunctional materials with low temperature hydrogen storage, gas separation and energy storage properties.</div></div>\",\"PeriodicalId\":13599,\"journal\":{\"name\":\"Inorganica Chimica Acta\",\"volume\":\"575 \",\"pages\":\"Article 122414\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganica Chimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S002016932400505X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002016932400505X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
A porous three-dimensional Cu-MOF: Preparation and application in supercapacitors, low temperature hydrogen storage and gas separation
Due to its unique porosity, metal–organic frameworks (MOFs) have great application prospects in the fields of gas adsorption and separation. However, the synthesis of multi-functional MOFs is still a great challenge. Herein, a multi-functional Cu-MOF of {[Cu2(TPTA)(H2O)2]·2DMF·NMP·4H2O}n with a porosity of 62.0 % was designed and synthesized. The H2 adsorption amount of Cu-MOF is about 289.2 cm3 g−1 at 77 K and 1 bar. Meanwhile, the selectivity adsorption of Cu-MOF towards CO2 over CH4 (V:V = 0.5:0.5), CO2/N2 (V:V = 0.5:0.5) and CO2/H2 (V:V = 0.5:0.5) is 95.1, 139.2 and 147.5, respectively, which is 1.5 times higher than the previously reported Cu-MOFs. The Cu-MOF@NF//AC asymmetric supercapacitor demonstrates high specific capacitance (53.4 F g−1) and stability (90.3 % after 2000 cycles). Furthermore, this work presents a novel approach to design multifunctional materials with low temperature hydrogen storage, gas separation and energy storage properties.
期刊介绍:
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.