Nur Adi Saputra , Gustan Pari , Wasrin Syafii , Deded Sarip Nawawi , Akhiruddin Maddu , Nidya Chitraningrum , Slamet Priyono
{"title":"利用化学活化的红色马蹄莲制备新型超级电容器及其应用","authors":"Nur Adi Saputra , Gustan Pari , Wasrin Syafii , Deded Sarip Nawawi , Akhiruddin Maddu , Nidya Chitraningrum , Slamet Priyono","doi":"10.1016/j.matchemphys.2024.130104","DOIUrl":null,"url":null,"abstract":"<div><div>In recent years, supercapacitors have been incorporated into hypercar units, making them more attractive to researchers. The exploration and development of low-cost supercap components are investigated for mass production preparation. The current study reveals an activated carbon-based supercapacitor from a novel biomass red calliandra. The activated carbon was chemically produced at 800 for 60 min in a pilot-scale tubular electric reactor with a capacity of 3 kg. Previously, the raw was soaked by phosphate (H) and ammonium (NH) compounds for 18 h. Activated carbon was then used to assemble the supercapacitor with the respective active slurry composition: activated carbon, conductive carbon, adhesive 80:10:10 (<em>w/w</em>), and LiPF<sub>6</sub> electrolyte. The products were characterised by proximate, ultimate, iodine adsorption, surface area analyser, X-ray diffraction, infrared spectrum, cyclic voltammetry (CV), and Galvanostatic charge-discharge (GCD). H-activated carbon is hygroscopic and exhibits a crystalline structure, while NH-activated carbon has the highest adsorption and surface area of 757 mg/g and 627 m<sup>2</sup>/g. CV and GCD agreed to establish the H-supercap as the best prototype by exhibiting specific capacitances of 146 and 167 F/g. Comparative studies were further summarised to evaluate a novel species among the previous raws and the suitability of the preferred activated carbon characteristics for supercapacitor fabrication. The results crowned the red calliandra species at a decent rank among them and were suitable for sustainable green campaigns.</div></div>","PeriodicalId":18227,"journal":{"name":"Materials Chemistry and Physics","volume":"329 ","pages":"Article 130104"},"PeriodicalIF":4.3000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and application of a novel supercapacitor from chemically activated red calliandra\",\"authors\":\"Nur Adi Saputra , Gustan Pari , Wasrin Syafii , Deded Sarip Nawawi , Akhiruddin Maddu , Nidya Chitraningrum , Slamet Priyono\",\"doi\":\"10.1016/j.matchemphys.2024.130104\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In recent years, supercapacitors have been incorporated into hypercar units, making them more attractive to researchers. The exploration and development of low-cost supercap components are investigated for mass production preparation. The current study reveals an activated carbon-based supercapacitor from a novel biomass red calliandra. The activated carbon was chemically produced at 800 for 60 min in a pilot-scale tubular electric reactor with a capacity of 3 kg. Previously, the raw was soaked by phosphate (H) and ammonium (NH) compounds for 18 h. Activated carbon was then used to assemble the supercapacitor with the respective active slurry composition: activated carbon, conductive carbon, adhesive 80:10:10 (<em>w/w</em>), and LiPF<sub>6</sub> electrolyte. The products were characterised by proximate, ultimate, iodine adsorption, surface area analyser, X-ray diffraction, infrared spectrum, cyclic voltammetry (CV), and Galvanostatic charge-discharge (GCD). H-activated carbon is hygroscopic and exhibits a crystalline structure, while NH-activated carbon has the highest adsorption and surface area of 757 mg/g and 627 m<sup>2</sup>/g. CV and GCD agreed to establish the H-supercap as the best prototype by exhibiting specific capacitances of 146 and 167 F/g. Comparative studies were further summarised to evaluate a novel species among the previous raws and the suitability of the preferred activated carbon characteristics for supercapacitor fabrication. The results crowned the red calliandra species at a decent rank among them and were suitable for sustainable green campaigns.</div></div>\",\"PeriodicalId\":18227,\"journal\":{\"name\":\"Materials Chemistry and Physics\",\"volume\":\"329 \",\"pages\":\"Article 130104\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Chemistry and Physics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S025405842401232X\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry and Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S025405842401232X","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation and application of a novel supercapacitor from chemically activated red calliandra
In recent years, supercapacitors have been incorporated into hypercar units, making them more attractive to researchers. The exploration and development of low-cost supercap components are investigated for mass production preparation. The current study reveals an activated carbon-based supercapacitor from a novel biomass red calliandra. The activated carbon was chemically produced at 800 for 60 min in a pilot-scale tubular electric reactor with a capacity of 3 kg. Previously, the raw was soaked by phosphate (H) and ammonium (NH) compounds for 18 h. Activated carbon was then used to assemble the supercapacitor with the respective active slurry composition: activated carbon, conductive carbon, adhesive 80:10:10 (w/w), and LiPF6 electrolyte. The products were characterised by proximate, ultimate, iodine adsorption, surface area analyser, X-ray diffraction, infrared spectrum, cyclic voltammetry (CV), and Galvanostatic charge-discharge (GCD). H-activated carbon is hygroscopic and exhibits a crystalline structure, while NH-activated carbon has the highest adsorption and surface area of 757 mg/g and 627 m2/g. CV and GCD agreed to establish the H-supercap as the best prototype by exhibiting specific capacitances of 146 and 167 F/g. Comparative studies were further summarised to evaluate a novel species among the previous raws and the suitability of the preferred activated carbon characteristics for supercapacitor fabrication. The results crowned the red calliandra species at a decent rank among them and were suitable for sustainable green campaigns.
期刊介绍:
Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.