Real-time measurement of metals in submicron aerosols with particle-into-liquid sampler combined with micro-discharge optical emission spectroscopy

The paper presents a novel technique for quantifying trace metals in aerosol samples in real time. Airborne metals were continuously collected for one week near the Baltic Sea in Finland using a particle-into-liquid sampler (PILS). The collected liquid samples were analyzed for metals using micro-discharge optical emission spectroscopy (µDOES). The micro-discharge analyzer is designed to perform real-time, on-site measurements of metal concentrations in aqueous solutions. Currently, µDOES can provide online measurements of 30 metals, with typical detection limits from 0.01 µg/m³ to 0.06 µg/m³ with a long-term repeatability less than 5%. The novelty of this analyzer lies in its compact design, rapid detection capabilities, and ease of operation and maintenance. Several metals, including potassium (K), calcium (Ca), sodium (Na), aluminum (Al), magnesium (Mg), and copper (Cu), were measured in the aerosol samples collected using PILS. The results indicate that this approach has significant potential for future automated online monitoring of airborne metal concentrations, facilitating investigations into their sources and daily variations. The development of real-time technologies for rapid, online, and accurate atmospheric aerosol measurements is essential for advancing climate change research. Such advancements allowing for continuous real-time data enhance our understanding of aerosol dynamics, improve source identification, and inform public health and environmental policies, ultimately contributing to more effective climate change monitoring and mitigation.