{"title":"不同过渡金属和钠与萨伦型隔室配体的异核配合物的合成、结构和不同应用综述","authors":"","doi":"10.1016/j.ica.2024.122405","DOIUrl":null,"url":null,"abstract":"<div><div>Salen-type compartmental ligands, prepared by the 1:2 condensation of a diamine and a salicylaldehyde derivative, have been used in the synthesis of a variety of hereto-nuclear complexes with several transition and non-transition metals. This review focuses light on the synthesis of different hetero-nuclear transition metal/Na complexes with these ‘salen type’ compartmental Schiff base ligands. The X-ray structures, properties and different applications of these complexes are also discussed. The less explored area is also highlighted.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An overview of the synthesis, structure and different applications of hetero-nuclear complexes of different transition metals and sodium with salen type compartmental ligands\",\"authors\":\"\",\"doi\":\"10.1016/j.ica.2024.122405\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Salen-type compartmental ligands, prepared by the 1:2 condensation of a diamine and a salicylaldehyde derivative, have been used in the synthesis of a variety of hereto-nuclear complexes with several transition and non-transition metals. This review focuses light on the synthesis of different hetero-nuclear transition metal/Na complexes with these ‘salen type’ compartmental Schiff base ligands. The X-ray structures, properties and different applications of these complexes are also discussed. The less explored area is also highlighted.</div></div>\",\"PeriodicalId\":13599,\"journal\":{\"name\":\"Inorganica Chimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganica Chimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0020169324004961\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169324004961","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
摘要
通过二胺和水杨醛衍生物 1:2 缩合制备的沙仑型室配体已被用于合成多种过渡金属和非过渡金属的核络合物。本综述重点介绍了与这些 "水杨醛型 "隔室席夫碱配体合成不同异核过渡金属/Na 配合物的情况。此外,还讨论了这些配合物的 X 射线结构、性质和不同应用。此外,还重点介绍了探索较少的领域。
An overview of the synthesis, structure and different applications of hetero-nuclear complexes of different transition metals and sodium with salen type compartmental ligands
Salen-type compartmental ligands, prepared by the 1:2 condensation of a diamine and a salicylaldehyde derivative, have been used in the synthesis of a variety of hereto-nuclear complexes with several transition and non-transition metals. This review focuses light on the synthesis of different hetero-nuclear transition metal/Na complexes with these ‘salen type’ compartmental Schiff base ligands. The X-ray structures, properties and different applications of these complexes are also discussed. The less explored area is also highlighted.
期刊介绍:
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.