{"title":"用修正的移位莫尔斯势理论计算钠二聚体的热力学函数","authors":"U.S. Okorie, G.J. Rampho","doi":"10.1016/j.comptc.2024.114925","DOIUrl":null,"url":null,"abstract":"<div><div>In this article, the asymptotic iteration method and the Laguerre polynomials are employed to obtain the eigensolutions of the Schrödinger equation with modified shifted Morse potential model. Vibrational energy results for sodium dimer have been presented numerically and these results are compared with experimental data from available literatures. With the help of the energy expression, the partition function and other thermodynamic function expressions of this potential model for sodium dimer are obtained, using the Euler MacLaurin’s formula. For various vibrational quantum numbers considered, the thermodynamic functions show high level of dependence on the temperature parameter. These results are justified by the numerical results presented for the thermodynamic functions of sodium dimer. Our results also agree with the available results in literatures and can also serve as a guiding reference in further studies concerning chemical physics and spectroscopy.</div></div>","PeriodicalId":284,"journal":{"name":"Computational and Theoretical Chemistry","volume":"1241 ","pages":"Article 114925"},"PeriodicalIF":3.0000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Theoretical computation of thermodynamic functions of sodium dimer with modified shifted Morse potential\",\"authors\":\"U.S. Okorie, G.J. Rampho\",\"doi\":\"10.1016/j.comptc.2024.114925\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this article, the asymptotic iteration method and the Laguerre polynomials are employed to obtain the eigensolutions of the Schrödinger equation with modified shifted Morse potential model. Vibrational energy results for sodium dimer have been presented numerically and these results are compared with experimental data from available literatures. With the help of the energy expression, the partition function and other thermodynamic function expressions of this potential model for sodium dimer are obtained, using the Euler MacLaurin’s formula. For various vibrational quantum numbers considered, the thermodynamic functions show high level of dependence on the temperature parameter. These results are justified by the numerical results presented for the thermodynamic functions of sodium dimer. Our results also agree with the available results in literatures and can also serve as a guiding reference in further studies concerning chemical physics and spectroscopy.</div></div>\",\"PeriodicalId\":284,\"journal\":{\"name\":\"Computational and Theoretical Chemistry\",\"volume\":\"1241 \",\"pages\":\"Article 114925\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Computational and Theoretical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2210271X2400464X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Computational and Theoretical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2210271X2400464X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Theoretical computation of thermodynamic functions of sodium dimer with modified shifted Morse potential
In this article, the asymptotic iteration method and the Laguerre polynomials are employed to obtain the eigensolutions of the Schrödinger equation with modified shifted Morse potential model. Vibrational energy results for sodium dimer have been presented numerically and these results are compared with experimental data from available literatures. With the help of the energy expression, the partition function and other thermodynamic function expressions of this potential model for sodium dimer are obtained, using the Euler MacLaurin’s formula. For various vibrational quantum numbers considered, the thermodynamic functions show high level of dependence on the temperature parameter. These results are justified by the numerical results presented for the thermodynamic functions of sodium dimer. Our results also agree with the available results in literatures and can also serve as a guiding reference in further studies concerning chemical physics and spectroscopy.
期刊介绍:
Computational and Theoretical Chemistry publishes high quality, original reports of significance in computational and theoretical chemistry including those that deal with problems of structure, properties, energetics, weak interactions, reaction mechanisms, catalysis, and reaction rates involving atoms, molecules, clusters, surfaces, and bulk matter.