咪唑基离子液体与水的润湿和界面行为：全面综述

IF 2.8 3区工程技术 Q3 CHEMISTRY, PHYSICAL

Fluid Phase Equilibria Pub Date : 2024-10-11 DOI:10.1016/j.fluid.2024.114252

Sanchari Bhattacharjee, Devargya Chakraborty, Sandip Khan

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引用次数: 0

摘要

离子液体（IL）因其多样化的应用而备受关注，尤其是在控制特定固体基底的润湿性方面，这对依赖于包括粘附和润湿在内的界面行为的各种工艺都有影响。本综述涵盖了 IL 润湿行为及其影响方面的主要进展。液滴大小、温度、烷基链结构、阴离子类型、水浓度和外部电场等因素都会影响 IL 及其水溶液的接触角。尽管 IL 特性易受含水量的影响以及润湿性测量对固体表面的敏感性带来了挑战，但本综述仍对 IL 润湿研究的范围进行了导航，探讨了线张力、表面张力测量和氢键等问题。本研究旨在提供有关 IL 润湿动力学的深刻见解，为基于 IL 的流体技术设计提供信息，并阐明类似复杂流体中错综复杂的静态和动态润湿属性。

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Wetting and interfacial behavior of imidazolium-based ionic liquids and water: A comprehensive review

Ionic liquids (ILs) have garnered considerable attention for their diverse applications, notably in controlling wettability on specific solid substrates, which holds ramifications for various processes reliant on interfacial behaviour encompassing adhesion and wetting. This review encompasses key advancements in IL wetting behavior and its implications. Factors such as drop size, temperature, alkyl chain structure, anion type, water concentration, and external electric fields influence the contact angle of ILs and their aqueous solutions. Despite challenges arising from IL property susceptibility to water content and wettability measurement sensitivity to solid surface, this review navigates the extent of IL wetting research, addressing line tension, surface tension measurement, and hydrogen bonding. The study aspires to furnish profound insights into IL wetting dynamics, informing IL-based fluidic technology design and elucidating intricate static and dynamic wetting attributes in analogous complex fluids.

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来源期刊

Fluid Phase Equilibria 工程技术-工程：化工

CiteScore

5.30

自引率

15.40%

发文量

223

审稿时长

53 days

期刊介绍： Fluid Phase Equilibria publishes high-quality papers dealing with experimental, theoretical, and applied research related to equilibrium and transport properties of fluids, solids, and interfaces. Subjects of interest include physical/phase and chemical equilibria; equilibrium and nonequilibrium thermophysical properties; fundamental thermodynamic relations; and stability. The systems central to the journal include pure substances and mixtures of organic and inorganic materials, including polymers, biochemicals, and surfactants with sufficient characterization of composition and purity for the results to be reproduced. Alloys are of interest only when thermodynamic studies are included, purely material studies will not be considered. In all cases, authors are expected to provide physical or chemical interpretations of the results. Experimental research can include measurements under all conditions of temperature, pressure, and composition, including critical and supercritical. Measurements are to be associated with systems and conditions of fundamental or applied interest, and may not be only a collection of routine data, such as physical property or solubility measurements at limited pressures and temperatures close to ambient, or surfactant studies focussed strictly on micellisation or micelle structure. Papers reporting common data must be accompanied by new physical insights and/or contemporary or new theory or techniques.