Marta Porcaro, Miguel Sanz-Abad, Laura Michetti, Alessandro Conti, Caterina De Vito, María Teresa Doménech-Carbó, Antonio Doménech-Carbó
{"title":"固定颗粒伏安法与金属腐蚀铜绿的莫特-肖特基分析之间的相关性。","authors":"Marta Porcaro, Miguel Sanz-Abad, Laura Michetti, Alessandro Conti, Caterina De Vito, María Teresa Doménech-Carbó, Antonio Doménech-Carbó","doi":"10.1002/cphc.202400805","DOIUrl":null,"url":null,"abstract":"<p><p>The conjoint application of the voltammetry of immobilized particles (VIMP) methodology and the Mott-Schottky analysis (MS) of impedance data to studying metal corrosion patinas is described. The study is applied to copper and bronze objects exploiting the semiconducting character of cuprite and other copper corrosion products. A simplified theoretical modeling of MS analysis at microparticulate deposits extracted from metal corrosion layers attached to graphite electrodes is provided. The proposed model compensates for the disturbing effect of the regions of the basal electrode directly exposed to the electrolyte. Alternative models accounting for the variation of the density of charge carriers with depth are tested as well as the correlation between VIMP and MS data with reasonably satisfactory results.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400805"},"PeriodicalIF":2.3000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Correlation Between Voltammetry of Immobilized Particles and Mott-Schottky Analysis of Metal Corrosion Patinas.\",\"authors\":\"Marta Porcaro, Miguel Sanz-Abad, Laura Michetti, Alessandro Conti, Caterina De Vito, María Teresa Doménech-Carbó, Antonio Doménech-Carbó\",\"doi\":\"10.1002/cphc.202400805\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The conjoint application of the voltammetry of immobilized particles (VIMP) methodology and the Mott-Schottky analysis (MS) of impedance data to studying metal corrosion patinas is described. The study is applied to copper and bronze objects exploiting the semiconducting character of cuprite and other copper corrosion products. A simplified theoretical modeling of MS analysis at microparticulate deposits extracted from metal corrosion layers attached to graphite electrodes is provided. The proposed model compensates for the disturbing effect of the regions of the basal electrode directly exposed to the electrolyte. Alternative models accounting for the variation of the density of charge carriers with depth are tested as well as the correlation between VIMP and MS data with reasonably satisfactory results.</p>\",\"PeriodicalId\":9819,\"journal\":{\"name\":\"Chemphyschem\",\"volume\":\" \",\"pages\":\"e202400805\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemphyschem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/cphc.202400805\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemphyschem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cphc.202400805","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
本文介绍了固定颗粒伏安法（VIMP）和阻抗数据莫特-肖特基分析法（MS）在研究金属腐蚀铜绿的联合应用。该研究利用铜绿石和其他铜腐蚀产物的半导体特性，将其应用于铜和青铜物体。本文提供了一个简化的 MS 分析理论模型，用于分析从附着在石墨电极上的金属腐蚀层中提取的微粒沉积物。提出的模型补偿了直接暴露在电解液中的基极区域的干扰效应。还测试了电荷载体密度随深度变化的其他模型，以及 VIMP 和 MS 数据之间的相关性，结果相当令人满意。
Correlation Between Voltammetry of Immobilized Particles and Mott-Schottky Analysis of Metal Corrosion Patinas.
The conjoint application of the voltammetry of immobilized particles (VIMP) methodology and the Mott-Schottky analysis (MS) of impedance data to studying metal corrosion patinas is described. The study is applied to copper and bronze objects exploiting the semiconducting character of cuprite and other copper corrosion products. A simplified theoretical modeling of MS analysis at microparticulate deposits extracted from metal corrosion layers attached to graphite electrodes is provided. The proposed model compensates for the disturbing effect of the regions of the basal electrode directly exposed to the electrolyte. Alternative models accounting for the variation of the density of charge carriers with depth are tested as well as the correlation between VIMP and MS data with reasonably satisfactory results.
期刊介绍：
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
