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引用次数: 0
摘要
氧化石墨烯(GO)膜具有良好的结构和化学性质,包括高透水性、耐化学性和机械强度,因此作为一种有前途的选择性渗透分离材料,已受到广泛关注。在本研究中,我们探讨了 GO 膜在渗透分离液体混合物中的潜在应用。GO 膜的层状结构和亲水性能有利于水通过埃级的层间间隔进行快速和选择性的传输,因此其性能优于传统的聚合物膜和无机膜。独特的质量传输机制--滑流和分子排列--使 GO 膜能够选择性地渗透水而不是有机溶剂。在化学脱水方面,GO 膜是最有潜力的候选材料。此外,还讨论了提高 GO 膜稳定性和分离性能的复合 GO 膜和交联技术的进展。本研究强调了 GO 膜在推进膜分离和促进环境可持续性方面的作用,从而突出了 GO 膜的优势及其替代或补充现有技术的潜力。未来的研究有望优化 GO 膜的制造技术,并扩大其应用范围。
Graphene Oxide and its Composites: Advanced Membranes for Selective Water Permeation.
Graphene oxide (GO) membranes have gained significant attention as a promising material for separation by selective permeation processes due to their advantageous structural and chemical properties, including high water permeability, chemical resistance, and mechanical strength. In this study, we explore the potential applications of GO membranes in pervaporation to separate liquid mixtures. The layered structure and hydrophilic nature of GO membrane facilitate rapid and selective water transport through angstrom-scale interlayer spacings, resulting in superior performance over conventional polymeric and inorganic membranes. The unique mass transport mechanisms - slip flow and molecular alignment - enable GO membranes to selectively permeate water over organic solvents. For chemical dehydration, GO membranes are the most potential candidates. Furthermore, advancements in composite GO membranes and cross-linking techniques that improve their stability and separation performance are discussed. This study highlights the advantages of GO membranes and their potential to replace or complement existing technologies, by emphasizing their role in advancing membrane-based separation and promoting environmental sustainability. Future research is expected to optimize the fabrication techniques for GO membranes and expand their application scope.
期刊介绍:
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.