Pilot Assessment of Impacts of Ozone and Ozone/Hydrogen Peroxide Treatment on the Fate of Per- and Polyfluoroalkyl Substances and Precursors.

Per- and polyfluoroalkyl substances (PFAS) make up a large class of anthropogenic micropollutants prevalent in wastewater. Oxidative processes commonly used in wastewater potable reuse treatment may affect transformation of PFAS precursors, leading to elevated concentrations of perfluorinated alkyl acids (PFAAs) that are significant health concerns. This work conducted a pilot-scale investigation to assess the influence of ozonation (O₃) and ozone/hydrogen peroxide (O₃/H₂O₂) advanced oxidation process (AOP), respectively, on the fate of PFAS in a wastewater effluent subjected to reuse. The study evaluated 40 target PFAS and associated precursors [based on the total oxidizable precursor (TOP) assay] under various treatment conditions, including different ozone doses (1.0-4.0 mg·L^-1), H₂O₂ doses (0-0.20 mg·L^-1), and contact time (0-20 min). Results indicated that short-chain (C3-C7) PFAAs dominated in concentrations, while overall PFAA concentrations were elevated by both oxidative treatment processes, particularly after high-dose ozonation treatment. TOP assays revealed that there were considerable amounts of PFAA precursors in the reuse wastewater, and their concentrations were decreased after the oxidative treatment with an increase of some of the PFAAs. This pilot study demonstrated that ozone and ozone-based AOP treatments can have a moderate influence on the transformation of PFAS and increase in PFAA levels under practical conditions.