作为氧进化催化剂的有机-无机杂化含钴多氧钨酸盐†

IF 2.6 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

CrystEngComm Pub Date : 2024-10-01 DOI:10.1039/D4CE00873A

Zhe-Hong Chen, Xiao-Yue Zhang, Da-Huan Li, Xin-Xiong Li, Yan-Qiong Sun, Cai Sun and Shou-Tian Zheng

{"title":"作为氧进化催化剂的有机-无机杂化含钴多氧钨酸盐†","authors":"Zhe-Hong Chen, Xiao-Yue Zhang, Da-Huan Li, Xin-Xiong Li, Yan-Qiong Sun, Cai Sun and Shou-Tian Zheng","doi":"10.1039/D4CE00873A","DOIUrl":null,"url":null,"abstract":"<p >Herein, cobalt is incorporated into a polyoxotungstate (POW) to obtain a new organic–inorganic hybrid Co-containing POW with a reliable 1D nanowire structure. The Co-containing POW exhibits superior oxygen evolution reaction (OER) activity in a neutral medium compared with its isomorphic Zn-containing POW, highlighting the critical role of cobalt in enhancing OER performance. This work provides a new insight into the structure–property relationship of metal oxides in electrocatalysis.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 41","pages":" 5840-5844"},"PeriodicalIF":2.6000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organic–inorganic hybrid Co-containing polyoxotungstate as an oxygen evolution catalyst†\",\"authors\":\"Zhe-Hong Chen, Xiao-Yue Zhang, Da-Huan Li, Xin-Xiong Li, Yan-Qiong Sun, Cai Sun and Shou-Tian Zheng\",\"doi\":\"10.1039/D4CE00873A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Herein, cobalt is incorporated into a polyoxotungstate (POW) to obtain a new organic–inorganic hybrid Co-containing POW with a reliable 1D nanowire structure. The Co-containing POW exhibits superior oxygen evolution reaction (OER) activity in a neutral medium compared with its isomorphic Zn-containing POW, highlighting the critical role of cobalt in enhancing OER performance. This work provides a new insight into the structure–property relationship of metal oxides in electrocatalysis.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 41\",\"pages\":\" 5840-5844\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00873a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00873a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

在本文中，钴被加入到聚氧化钨酸盐（POW）中，从而获得了一种具有可靠一维纳米线结构的新型有机-无机杂化含钴 POW。与同构的含锌 POW 相比，这种含 Co 的 POW 在中性介质中表现出更高的氧进化反应（OER）活性，突出了钴在提高 OER 性能方面的关键作用。这项研究为了解电催化中金属氧化物的结构-性能关系提供了新的视角。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Organic–inorganic hybrid Co-containing polyoxotungstate as an oxygen evolution catalyst†

查看原文本刊更多论文

Organic–inorganic hybrid Co-containing polyoxotungstate as an oxygen evolution catalyst†

Herein, cobalt is incorporated into a polyoxotungstate (POW) to obtain a new organic–inorganic hybrid Co-containing POW with a reliable 1D nanowire structure. The Co-containing POW exhibits superior oxygen evolution reaction (OER) activity in a neutral medium compared with its isomorphic Zn-containing POW, highlighting the critical role of cobalt in enhancing OER performance. This work provides a new insight into the structure–property relationship of metal oxides in electrocatalysis.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊