{"title":"乙烯-醋酸乙烯-石墨烯纳米复合材料的开发与表征","authors":"Madhu Bilugali Mahadevaswamy, Rashmi Balasubramanya","doi":"10.1002/masy.202400076","DOIUrl":null,"url":null,"abstract":"<p>The prospective applications of carbon graphene nanoplatelets (GNPs) reinforced ethylene vinyl acetate (EVA) nanocomposites in flexible electronics, energy storage devices, and thermal management systems have attracted a lot of attention. These nanocomposites offer an effective solution for enhancing the electrical conductivity of interfacing materials in electronic systems and addressing issues related to thermal management. GNPs that possess excellent thermal conductivity of 2000–4000 W m<sup>−1</sup> K<sup>−1</sup> and an electrical conductivity of 10<sup>7</sup> S m<sup>−1</sup> are utilized in this investigation. The homogeneous dispersion of nanofiller and the effective load transfer between components through strong filler/polymer interfacial interactions are essential for the creation of multifunctional polymer nanocomposites. Particularly, their electrical conductivity and dielectric properties are highlighted in this study, with an emphasis on the synthesis and characterization of nanocomposite materials. This work investigates the utilization of graphene nanocomposites in EVA using a melt-mixing technique assisted by sonication to fabricate multifunctional composites. Incorporating different weight percentages of GNPs (ranging from 0.1 to 0.4 wt.%) within the polymer matrix is carried out. In the present study, the nanocomposites are characterized by scanning electron microscopy investigation and impedance spectrum analysis. The distinctive characteristics of the AC electrical transport in nanocomposites are investigated between 10 Hz and 1 MHz. Excellent interfacial compatibility has been demonstrated by the homogenous distribution of GNPs within the matrix, confirmed by SEM examination. These EVA nanocomposites demonstrate improved electrical conductivity, thereby rendering them very useful for energy storage applications, such as electronic capacitors, wherein supports with a significant dielectric constant and minimal dielectric loss are required.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"413 5","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development and Characterization of Ethylene-Vinyl Acetate-Graphene Nanocomposites\",\"authors\":\"Madhu Bilugali Mahadevaswamy, Rashmi Balasubramanya\",\"doi\":\"10.1002/masy.202400076\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The prospective applications of carbon graphene nanoplatelets (GNPs) reinforced ethylene vinyl acetate (EVA) nanocomposites in flexible electronics, energy storage devices, and thermal management systems have attracted a lot of attention. These nanocomposites offer an effective solution for enhancing the electrical conductivity of interfacing materials in electronic systems and addressing issues related to thermal management. GNPs that possess excellent thermal conductivity of 2000–4000 W m<sup>−1</sup> K<sup>−1</sup> and an electrical conductivity of 10<sup>7</sup> S m<sup>−1</sup> are utilized in this investigation. The homogeneous dispersion of nanofiller and the effective load transfer between components through strong filler/polymer interfacial interactions are essential for the creation of multifunctional polymer nanocomposites. Particularly, their electrical conductivity and dielectric properties are highlighted in this study, with an emphasis on the synthesis and characterization of nanocomposite materials. This work investigates the utilization of graphene nanocomposites in EVA using a melt-mixing technique assisted by sonication to fabricate multifunctional composites. Incorporating different weight percentages of GNPs (ranging from 0.1 to 0.4 wt.%) within the polymer matrix is carried out. In the present study, the nanocomposites are characterized by scanning electron microscopy investigation and impedance spectrum analysis. The distinctive characteristics of the AC electrical transport in nanocomposites are investigated between 10 Hz and 1 MHz. Excellent interfacial compatibility has been demonstrated by the homogenous distribution of GNPs within the matrix, confirmed by SEM examination. These EVA nanocomposites demonstrate improved electrical conductivity, thereby rendering them very useful for energy storage applications, such as electronic capacitors, wherein supports with a significant dielectric constant and minimal dielectric loss are required.</p>\",\"PeriodicalId\":18107,\"journal\":{\"name\":\"Macromolecular Symposia\",\"volume\":\"413 5\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Symposia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/masy.202400076\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/masy.202400076","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0
摘要
碳石墨烯纳米片(GNPs)增强醋酸乙烯(EVA)纳米复合材料在柔性电子器件、储能设备和热管理系统中的应用前景备受关注。这些纳米复合材料为增强电子系统中界面材料的导电性和解决热管理相关问题提供了有效的解决方案。本研究采用的 GNP 具有 2000-4000 W m-1 K-1 的优异热导率和 107 S m-1 的电导率。纳米填料的均匀分散以及通过填料/聚合物之间的强烈界面相互作用实现各组分之间的有效负载传递,对于制造多功能聚合物纳米复合材料至关重要。本研究特别强调了纳米复合材料的导电性能和介电性质,重点是纳米复合材料的合成和表征。本研究采用超声辅助下的熔融混合技术,研究了石墨烯纳米复合材料在 EVA 中的应用,以制造多功能复合材料。在聚合物基体中加入不同重量百分比的 GNPs(0.1-0.4 wt.%)。本研究通过扫描电子显微镜研究和阻抗谱分析对纳米复合材料进行了表征。研究了纳米复合材料在 10 Hz 和 1 MHz 之间交流电传输的独特特性。经扫描电子显微镜检查证实,GNPs 在基体中的均匀分布证明了极佳的界面相容性。这些 EVA 纳米复合材料具有更高的导电性,因此非常适用于电子电容器等储能应用,这些应用需要具有较大介电常数和最小介电损耗的支撑物。
Development and Characterization of Ethylene-Vinyl Acetate-Graphene Nanocomposites
The prospective applications of carbon graphene nanoplatelets (GNPs) reinforced ethylene vinyl acetate (EVA) nanocomposites in flexible electronics, energy storage devices, and thermal management systems have attracted a lot of attention. These nanocomposites offer an effective solution for enhancing the electrical conductivity of interfacing materials in electronic systems and addressing issues related to thermal management. GNPs that possess excellent thermal conductivity of 2000–4000 W m−1 K−1 and an electrical conductivity of 107 S m−1 are utilized in this investigation. The homogeneous dispersion of nanofiller and the effective load transfer between components through strong filler/polymer interfacial interactions are essential for the creation of multifunctional polymer nanocomposites. Particularly, their electrical conductivity and dielectric properties are highlighted in this study, with an emphasis on the synthesis and characterization of nanocomposite materials. This work investigates the utilization of graphene nanocomposites in EVA using a melt-mixing technique assisted by sonication to fabricate multifunctional composites. Incorporating different weight percentages of GNPs (ranging from 0.1 to 0.4 wt.%) within the polymer matrix is carried out. In the present study, the nanocomposites are characterized by scanning electron microscopy investigation and impedance spectrum analysis. The distinctive characteristics of the AC electrical transport in nanocomposites are investigated between 10 Hz and 1 MHz. Excellent interfacial compatibility has been demonstrated by the homogenous distribution of GNPs within the matrix, confirmed by SEM examination. These EVA nanocomposites demonstrate improved electrical conductivity, thereby rendering them very useful for energy storage applications, such as electronic capacitors, wherein supports with a significant dielectric constant and minimal dielectric loss are required.
期刊介绍:
Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.