Kaiqiang Zhang, Chao Wu, Shiye Yan, Changlong Ma, Luoya Wang, Pei Kong, Kun Zhuang, Pengcheng Fan, Jilei Ye, Yuping Wu
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Inherent Water Competition Effect-Enabled Colloidal Electrode for Ultra-stable Aqueous Zn–I Batteries
Electrode material stability is crucial for the development of next-generation ultralong-lifetime batteries. However, current solid- and liquid-state electrode materials face challenges such as rigid atomic structure collapse and uncontrolled species migration, respectively, which contradict the theoretical requirements for ultralong operation lifetimes. Herein, we present a design concept for a soft colloid polyvinylpyrrolidone iodine (PVP-I) electrode, leveraging the inherent water molecule competition effect between (SO4)2– from the electrolyte and PVP-I from the cathode in an aqueous Zn||PVP-I battery. Electrochemical demonstrations measured under various simulated and practical (integrated with photovoltaic solar panel) conditions highlight the potential for an ultralong battery lifetime. The PVP-I colloid exhibits a dynamic response to the electric field during battery operation. More importantly, the water competition effect between (SO4)2– from the electrolyte and water-soluble polymer cathode materials establishes a new electrolyte/cathode interfacial design platform for advancing ultralong-lifetime aqueous batteries.
期刊介绍:
The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.