封面:二茚并熔芫荽烯-扩展四硫杂戊烯(ChemPhotoChem 10/2024)

IF 3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Dr. Viktor Bliksted Roug Pedersen, Prof. Dr. Ramesh Jasti, Prof. Dr. Mogens Brøndsted Nielsen
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引用次数: 0

摘要

封面展示了芫荽烯-扩展四硫代富勒烯的单电子氧化顺序以及伴随的颜色变化。结构中的圆圈突出显示了每种氧化还原态的克拉六元组。二价共振结构可以绘制出四种有利的克拉六次方,而二价共振结构只有两种有利的克拉六次方,由此看来二价共振结构具有一定的二价共振特性。更多信息,请参阅 Mogens Brøndsted Nielsen 及其合作者的研究文章(DOI 10.1002/cptc.202400122)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Front Cover: Diindeno-Fused Corannulene-Extended Tetrathiafulvalenes (ChemPhotoChem 10/2024)

Front Cover: Diindeno-Fused Corannulene-Extended Tetrathiafulvalenes (ChemPhotoChem 10/2024)

The Front Cover illustrates the sequential one-electron oxidations of corannulene-extended tetrathiafulvalene and the accompanying color changes. Clar sextets for each redox state are highlighted by filled circles within the structures. The dication seems to exhibit some diradicaloid character in line with the fact that four favorable Clar sextets can be drawn for the diradicaloid resonance structure and only two for the quinoid structure. More information can be found in the Research Article by Mogens Brøndsted Nielsen and co-workers (DOI 10.1002/cptc.202400122).

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来源期刊
ChemPhotoChem
ChemPhotoChem Chemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
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