Xinhao Shi , Liping Wang , Wanbo Hou , Jiahui Ding , Tao Feng , Hongjiao Lin , Mingde Tong
{"title":"不同热通量下多相 HfC-SiC 基复合材料的界面力学和烧蚀演化行为","authors":"Xinhao Shi , Liping Wang , Wanbo Hou , Jiahui Ding , Tao Feng , Hongjiao Lin , Mingde Tong","doi":"10.1016/j.jeurceramsoc.2024.116958","DOIUrl":null,"url":null,"abstract":"<div><div>Multiphase HfC-SiC ceramic matrix composites were prepared by a combination process. The interface mechanics and ablation properties behaviors were investigated. Introducing the PyC-SiC interface, the composites showed a second-order pull-out mechanism. The mechanical failure model showed that fibers and matrix have different failure strain under load depending on the component that fails first. Moreover, the ablative airflow in the center area will spread to the edge area through the thermal shock microcracks generated. Increasing of the heat flux, the crack width gradually increased to be ditches. It accelerated the evolution of surface morphology, which showed HfC-SiC substrate was first transformed into Hf-Si-O solid solution on the process of phase transformation of oxidation products from 1680 ℃ to 2150 ℃, and eventually sintered into HfO<sub>2</sub>. The change in the morphology of oxidation product consumed more heat and protected the substrate from oxidation, resulting in improving the ablation resistance of composites.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"45 3","pages":"Article 116958"},"PeriodicalIF":5.8000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The interface mechanical and ablative evolution behaviors under different heat flux of multiphase HfC-SiC matrix composites\",\"authors\":\"Xinhao Shi , Liping Wang , Wanbo Hou , Jiahui Ding , Tao Feng , Hongjiao Lin , Mingde Tong\",\"doi\":\"10.1016/j.jeurceramsoc.2024.116958\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Multiphase HfC-SiC ceramic matrix composites were prepared by a combination process. The interface mechanics and ablation properties behaviors were investigated. Introducing the PyC-SiC interface, the composites showed a second-order pull-out mechanism. The mechanical failure model showed that fibers and matrix have different failure strain under load depending on the component that fails first. Moreover, the ablative airflow in the center area will spread to the edge area through the thermal shock microcracks generated. Increasing of the heat flux, the crack width gradually increased to be ditches. It accelerated the evolution of surface morphology, which showed HfC-SiC substrate was first transformed into Hf-Si-O solid solution on the process of phase transformation of oxidation products from 1680 ℃ to 2150 ℃, and eventually sintered into HfO<sub>2</sub>. The change in the morphology of oxidation product consumed more heat and protected the substrate from oxidation, resulting in improving the ablation resistance of composites.</div></div>\",\"PeriodicalId\":17408,\"journal\":{\"name\":\"Journal of The European Ceramic Society\",\"volume\":\"45 3\",\"pages\":\"Article 116958\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The European Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0955221924008318\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The European Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0955221924008318","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
The interface mechanical and ablative evolution behaviors under different heat flux of multiphase HfC-SiC matrix composites
Multiphase HfC-SiC ceramic matrix composites were prepared by a combination process. The interface mechanics and ablation properties behaviors were investigated. Introducing the PyC-SiC interface, the composites showed a second-order pull-out mechanism. The mechanical failure model showed that fibers and matrix have different failure strain under load depending on the component that fails first. Moreover, the ablative airflow in the center area will spread to the edge area through the thermal shock microcracks generated. Increasing of the heat flux, the crack width gradually increased to be ditches. It accelerated the evolution of surface morphology, which showed HfC-SiC substrate was first transformed into Hf-Si-O solid solution on the process of phase transformation of oxidation products from 1680 ℃ to 2150 ℃, and eventually sintered into HfO2. The change in the morphology of oxidation product consumed more heat and protected the substrate from oxidation, resulting in improving the ablation resistance of composites.
期刊介绍:
The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.