{"title":"褐煤对水溶液中镍离子的吸附作用","authors":"I. Yu. Zykov, V. E. Tsvetkov, N. I. Fedorova","doi":"10.3103/S1068364X24600593","DOIUrl":null,"url":null,"abstract":"<div><p>The sorption of nickel ions from aqueous solutions by lignite is investigated. Five lignite samples from different fields are considered. The samples are characterized by different ash content and yield of volatiles, as well as different elemental compositions and atomic ratios H/C and O/C. The sorptional capacity of lignites for nickel ions is found to be 0.25–0.33 mg/g. The degree of extraction is 80–97%. Comparison of the sorption properties shows that the lignite samples have greater sorptional capacity and degree of extraction for nickel ions than industrial AG-3 sorbent (by 0.2 and 62.0%, respectively). It is found that lignite removes nickel ions from solution by simple monomolecular adsorption, as described by the Langmuir equation. The adsorption process is described by a pseudo-second-order kinetic model. The time to reach sorptional equilibrium and maximum sorptional capacity is 30–40 min.</p></div>","PeriodicalId":519,"journal":{"name":"Coke and Chemistry","volume":"67 6","pages":"339 - 343"},"PeriodicalIF":0.4000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sorption of Nickel Ions from Aqueous Solutions by Lignite\",\"authors\":\"I. Yu. Zykov, V. E. Tsvetkov, N. I. Fedorova\",\"doi\":\"10.3103/S1068364X24600593\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The sorption of nickel ions from aqueous solutions by lignite is investigated. Five lignite samples from different fields are considered. The samples are characterized by different ash content and yield of volatiles, as well as different elemental compositions and atomic ratios H/C and O/C. The sorptional capacity of lignites for nickel ions is found to be 0.25–0.33 mg/g. The degree of extraction is 80–97%. Comparison of the sorption properties shows that the lignite samples have greater sorptional capacity and degree of extraction for nickel ions than industrial AG-3 sorbent (by 0.2 and 62.0%, respectively). It is found that lignite removes nickel ions from solution by simple monomolecular adsorption, as described by the Langmuir equation. The adsorption process is described by a pseudo-second-order kinetic model. The time to reach sorptional equilibrium and maximum sorptional capacity is 30–40 min.</p></div>\",\"PeriodicalId\":519,\"journal\":{\"name\":\"Coke and Chemistry\",\"volume\":\"67 6\",\"pages\":\"339 - 343\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coke and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S1068364X24600593\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coke and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1068364X24600593","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Sorption of Nickel Ions from Aqueous Solutions by Lignite
The sorption of nickel ions from aqueous solutions by lignite is investigated. Five lignite samples from different fields are considered. The samples are characterized by different ash content and yield of volatiles, as well as different elemental compositions and atomic ratios H/C and O/C. The sorptional capacity of lignites for nickel ions is found to be 0.25–0.33 mg/g. The degree of extraction is 80–97%. Comparison of the sorption properties shows that the lignite samples have greater sorptional capacity and degree of extraction for nickel ions than industrial AG-3 sorbent (by 0.2 and 62.0%, respectively). It is found that lignite removes nickel ions from solution by simple monomolecular adsorption, as described by the Langmuir equation. The adsorption process is described by a pseudo-second-order kinetic model. The time to reach sorptional equilibrium and maximum sorptional capacity is 30–40 min.
期刊介绍：
The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.
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