Zh. K. Myltykbaeva, A. V. Anisimov, Zh. T. Eshova, A. B. Seisembekova, M. B. Smaiyl
{"title":"Severnoe Buzachi 油田石油中的金属卟啉：紫外线、红外线和 EPR 研究","authors":"Zh. K. Myltykbaeva, A. V. Anisimov, Zh. T. Eshova, A. B. Seisembekova, M. B. Smaiyl","doi":"10.1134/S0040579523050238","DOIUrl":null,"url":null,"abstract":"<div><p>The spectrophotometric studies of vanadylporphyrin complexes isolated from the oil of the Severnoe Buzachi field with absorption maxima at 534 and 573 nm showed that the dominant compounds were etioporphyrins (ETIOs) and deoxophylloerythro-etioporphyrins (DPEPs), and that extraction with N,N-dimethylformamide allows extraction of vanadylporphyrin complexes from oil without destroying their structure. The ETIO/DPEP ratio of vanadylporphyrins was 1.14–2.17. The IR spectra of the isolated vanadylporphyrin fractions indicated that the content of free porphyrins was extremely low judging by the presence of deformation and out-of-plane vibrations of the NH group in the ranges 3250–3400 and 960–980 cm<sup>–1</sup>. This suggests that the extraction method for isolating vanadylporphyrins does not lead to their demetallization. The EPR spectral data confirmed the high concentration and purity of vanadylporphyrin, which correlates well with the UV spectral data and indicates that chromatographic purification and separation of the extract is efficient.</p></div>","PeriodicalId":798,"journal":{"name":"Theoretical Foundations of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metalloporphyrins of Oil from the Severnoe Buzachi Oil Field: UV, IR, and EPR Studies\",\"authors\":\"Zh. K. Myltykbaeva, A. V. Anisimov, Zh. T. Eshova, A. B. Seisembekova, M. B. Smaiyl\",\"doi\":\"10.1134/S0040579523050238\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The spectrophotometric studies of vanadylporphyrin complexes isolated from the oil of the Severnoe Buzachi field with absorption maxima at 534 and 573 nm showed that the dominant compounds were etioporphyrins (ETIOs) and deoxophylloerythro-etioporphyrins (DPEPs), and that extraction with N,N-dimethylformamide allows extraction of vanadylporphyrin complexes from oil without destroying their structure. The ETIO/DPEP ratio of vanadylporphyrins was 1.14–2.17. The IR spectra of the isolated vanadylporphyrin fractions indicated that the content of free porphyrins was extremely low judging by the presence of deformation and out-of-plane vibrations of the NH group in the ranges 3250–3400 and 960–980 cm<sup>–1</sup>. This suggests that the extraction method for isolating vanadylporphyrins does not lead to their demetallization. The EPR spectral data confirmed the high concentration and purity of vanadylporphyrin, which correlates well with the UV spectral data and indicates that chromatographic purification and separation of the extract is efficient.</p></div>\",\"PeriodicalId\":798,\"journal\":{\"name\":\"Theoretical Foundations of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical Foundations of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0040579523050238\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical Foundations of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0040579523050238","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Metalloporphyrins of Oil from the Severnoe Buzachi Oil Field: UV, IR, and EPR Studies
The spectrophotometric studies of vanadylporphyrin complexes isolated from the oil of the Severnoe Buzachi field with absorption maxima at 534 and 573 nm showed that the dominant compounds were etioporphyrins (ETIOs) and deoxophylloerythro-etioporphyrins (DPEPs), and that extraction with N,N-dimethylformamide allows extraction of vanadylporphyrin complexes from oil without destroying their structure. The ETIO/DPEP ratio of vanadylporphyrins was 1.14–2.17. The IR spectra of the isolated vanadylporphyrin fractions indicated that the content of free porphyrins was extremely low judging by the presence of deformation and out-of-plane vibrations of the NH group in the ranges 3250–3400 and 960–980 cm–1. This suggests that the extraction method for isolating vanadylporphyrins does not lead to their demetallization. The EPR spectral data confirmed the high concentration and purity of vanadylporphyrin, which correlates well with the UV spectral data and indicates that chromatographic purification and separation of the extract is efficient.
期刊介绍：
Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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