双-(μ2-5-nona-noylquinolin-8-olato)双-[水合二氯化铟(III)]的晶体结构。

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-09-01 DOI:10.1107/S205698902400882X

Betty Fuhrmann , Eric Meier , Monika Mazik

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引用次数: 0

摘要

在这个名为 [In2(C18H22NO2)2Cl4(H2O)2] 的复合物中，每个铟离子都与两个氯离子、一个水分子和两个 8-喹啉酸根离子配位。由于 Owater-H⋯O=C 和 Owater-H⋯Cl 氢键的连接以及分叉的 Carene-H⋯Cl 接触，标题配合物的晶体由二维超分子聚集体组成。

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Crystal structure of bis(μ2-5-nonanoylquinolin-8-olato)bis[aquadichloridoindium(III)]

An analysis of the complex structure obtained by crystallization of 5-nonanoyl-8-hydroxyquinoline and InCl₃ in acetonitrile is reported.

Crystallization of 5-nonanoyl-8-hydroxyquinoline in the presence of InCl₃ in acetonitrile yields a dinuclear In^III complex crystallizing in the space group P

. In this complex, [In₂(C₁₈H₂₂NO₂)₂Cl₄(H₂O)₂], each indium ion is sixfold coordinated by two chloride ions, one water molecule and two 8-quinolinolate ions. The crystal of the title complex is composed of two-dimensional supramolecular aggregates, resulting from the linkage of the O_water—H⋯O=C and O_water—H⋯Cl hydrogen bonds as well as bifurcated C_arene—H⋯Cl contacts.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.