六-双-(1-甲基-1H-咪唑-κN 3)二硝酸锌(II)的合成、表征和晶体结构。

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-09-01 DOI:10.1107/S2056989024008806

Nomampondo Penelope Magwa , Thompho Jason Rashamuse

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引用次数: 0

摘要

本文描述了标题化合物[Zn(C4H6N2)6](NO3)2 的合成过程。该复合物由一个中心锌金属离子和六个 1-甲基咪唑配体组成，并由两个硝酸根阴离子平衡电荷。在晶体中，硝酸根离子位于[Zn(N-Melm)6]2+阳离子形成的空腔内，起着反离子的作用。硝酸根离子的三个氧原子参与微弱的 C-H⋯O 相互作用。除了单晶 X 射线衍射分析外，还利用元素分析、1H NMR、13C NMR 和傅立叶变换红外光谱对该复合物进行了表征。

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Synthesis, characterization, and crystal structure of hexakis(1-methyl-1H-imidazole-κN3)zinc(II) dinitrate

The title complex, which consists of a central zinc metal ion surrounded by six 1-methylimidazole ligands, charge balanced by two nitrate anions and which crystallizes in the space group P

has been synthesized and its structure determined.

The synthesis of the title compound, [Zn(C₄H₆N₂)₆](NO₃)₂, is described. This complex consists of a central zinc metal ion surrounded by six 1-methylimidazole ligands, charge balanced by two nitrate anions. The complex crystallizes in the space group P

. In the crystal, the nitrate ions are situated within the cavities created by the [Zn(N-Melm)₆]²⁺ cations, serving as counter-ions. The three oxygen atoms of the nitrate ion engage in weak C—H⋯O interactions. In addition to single-crystal X-ray diffraction analysis, the complex was characterized using elemental analysis, ¹H NMR, ¹³C NMR, and FTIR spectroscopy.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.