三重激子的调控自旋翻转:通过多样化电子捐献单元实现 MR-TADF 发射器,从而实现溶液加工的窄带有机发光二极管

IF 7.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Shengyu Li, Zhi Yang, Yanchao Xie, Lei Hua, Shian Ying, Yuchao Liu, Zhongjie Ren and Shouke Yan
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引用次数: 0

摘要

多重共振热激活延迟荧光(MR-TADF)分子正逐渐成为高分辨率有机发光二极管(OLED)显示器的理想候选分子,但由于激发态单重态和三重态之间的自旋轨道耦合强度较低,MR-TADF 发光体总是存在令人不满意的反向系统间交叉速率常数(kRISC)问题。在此,我们系统地研究了长程电荷转移(LRCT)和重原子对通过将多样化的电子供能单元与磁共振骨架整合来调节激发态性质和能级的影响。与未取代的类似物相比,新设计的 MR-TADF 发射器显著提高了 kRISC 值和接近统一的光量子产率,特别是在 tBuBNCz-PXZ (2.5×105 s-1) 和 tBuBNCz-Ph-PSeZ (2.1×105 s-1) 方面。利用这些优异特性,基于 tBuBNCz-PXZ 和 tBuBNCz-Ph-PSeZ 的溶液处理 OLED 的最大外部量子效率值可达到 21.3% 和 19.4%,在未采用额外敏化剂的溶液处理 MR-TADF 双元 OLED 中处于第一梯队。这项研究为通过快速调节 LRCT 和重原子效应来调节 MR-TADF 发射器的光电特性提供了一个框架。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Modulatory spin-flip of triplet excitons via diversiform electron-donating units for MR-TADF emitters towards solution-processed narrowband OLEDs†

Modulatory spin-flip of triplet excitons via diversiform electron-donating units for MR-TADF emitters towards solution-processed narrowband OLEDs†

Multiple resonance thermally activated delayed fluorescence (MR-TADF) molecules are emerging as promising candidates for high-resolution organic light-emitting diode (OLED) displays, but MR-TADF emitters always suffer from an unsatisfactory rate constant of reverse intersystem crossing (kRISC) due to inherently low spin orbital coupling strength between excited singlet and triplet states. Herein, we systematically investigate the long-range charge transfer (LRCT) and heavy-atom effects on modulating the excited state natures and energy levels via integrating diversiform electron-donating units with the MR skeleton. Compared with unsubstituted analogues, newly designed MR-TADF emitters exhibit significantly boosted kRISC values and close-to-unity photoluminescence quantum yield especially for tBuCzBN-PXZ (2.5 × 105 s−1) and tBuCzBN-Ph-PSeZ (2.1 × 105 s−1). Leveraging these exceptional properties, the maximum external quantum efficiency values of tBuCzBN-PXZ- and tBuCzBN-Ph-PSeZ-based solution-processed OLEDs can reach 21.3% and 19.4%, which are in the first tier of reported solution-processed MR-TADF binary OLEDs without employing additional sensitizers. This study provides a framework for modulating photoelectrical properties of MR-TADF emitters through fastidiously regulating LRCT and heavy-atom effects.

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来源期刊
Chemical Science
Chemical Science CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
14.40
自引率
4.80%
发文量
1352
审稿时长
2.1 months
期刊介绍: Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.
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