对 Re2O7 受控水合得到的 Re2O7.2H2O 加合物进行操作性光谱研究。

IF 2.3 3区化学 Q3 CHEMISTRY, PHYSICAL

Chemphyschem Pub Date : 2025-01-02 Epub Date: 2024-11-20 DOI:10.1002/cphc.202400432

Xavier Sécordel, Shreya Nandi, Asma Tougerti, Sylvain Cristol, Jean-François Paul, Valérie Briois, Camille La Fontaine, Elise Berrier

引用次数: 0

摘要

在此，我们利用拉曼、傅立叶变换红外和 XAS 技术对 Re2O7 的受控水合进行了全面的光谱研究，并辅以 ab initio 建模来确认光谱分配。因此，我们获得了 Re2O7.2H2O 的拉曼特征，并对其演化动力学进行了研究，从而详细描述了水合过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Operando Spectroscopic Investigation of the Re₂O₇.2H₂O Adduct obtained by Controlled Hydration of Re₂O₇.

We provide here a comprehensive investigation spectroscopic of the controlled hydration of Re₂O₇ using Raman, Fourier-Transform Infrared (FTIR) and X-Rays Absorption (XAS) techniques in complement with ab initio modelling for confirming the spectral assignments. Hence, the Raman signature of Re₂O₇.2H₂O was obtained, and the evolution kinetics was investigated to provide a detailed description of the hydration process.

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来源期刊

Chemphyschem 化学-物理：原子、分子和化学物理

CiteScore

4.60

自引率

3.40%

发文量

425

审稿时长

1.1 months

期刊介绍： ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.