带有四个嵌入式七芒星的负弯曲纳米石墨烯

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-09-27 DOI:10.1021/jacs.4c09185

Sven M. Elbert, Owen T. A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, Michael Mastalerz

{"title":"带有四个嵌入式七芒星的负弯曲纳米石墨烯","authors":"Sven M. Elbert, Owen T. A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, Michael Mastalerz","doi":"10.1021/jacs.4c09185","DOIUrl":null,"url":null,"abstract":"Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":null,"pages":null},"PeriodicalIF":14.4000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Negatively Curved Nanographene with Four Embedded Heptagons\",\"authors\":\"Sven M. Elbert, Owen T. A. Paine, Tobias Kirschbaum, Moritz P. Schuldt, Laura Weber, Frank Rominger, Michael Mastalerz\",\"doi\":\"10.1021/jacs.4c09185\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp2-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C76 cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C60 and C70 were studied.\",\"PeriodicalId\":49,\"journal\":{\"name\":\"Journal of the American Chemical Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":14.4000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/jacs.4c09185\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/jacs.4c09185","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

负弯曲纳米石墨被认为是三维全 sp2 杂化碳同素异形体（如施瓦茨石）的切口。在此，我们介绍了 Lenosky 等人提出的施瓦兹石 8-4-1-p 的 C76 切面的合成，并研究了其光学和电化学特性。此外，我们还研究了与富勒烯 C60 和 C70 的超分子相互作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A Negatively Curved Nanographene with Four Embedded Heptagons

查看原文本刊更多论文

A Negatively Curved Nanographene with Four Embedded Heptagons

Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp²-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C₇₆ cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C₆₀ and C₇₀ were studied.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.