热力学 IV 的单原子附加值:离子固体的公式体积、焓、绝对熵和热容量 - 水合物和无水物数据

Leslie Glasser
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引用次数: 0

摘要

原子和是化学元素的优化添加值,可用于预测无机固体的热化学值。由于原子和是以元素周期表中的元素为基础的,因此它们是一套完整的参数,只取决于是否有参考热化学数据。本出版物提供了无机水合物和无水物的环境公式单位体积、焓、熵和热容量的优化数据。这些数据补充了以前公布的形成反应熵和形成反应吉布斯能的原子和参数,并补充了以前公布的无差异无机固体的数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Additive single atom values for thermodynamics IV: Formula volume, enthalpy, absolute entropy and heat capacity for ionic solids - Hydrate and anhydrate data
Atom Sums are optimized additive values for the chemical elements which may be used to predict thermochemical values of inorganic solids. Since they are based on the elements of the Periodic Table they are a complete set of parameters, subject only to the availability of reference thermochemical data. In the present publication, optimized data is presented for ambient formula unit volumes, enthalpies, entropies and heat capacities for both inorganic hydrates and anhydrates. These data complement previously published Atom Sum parameters for formation reaction entropies and for formation reaction Gibbs energies as well as complementing earlier data for undifferentiated inorganic solids.
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