{"title":"从新热力学到经典力学","authors":"Henmei, Ni","doi":"10.26434/chemrxiv-2024-35kds-v4","DOIUrl":null,"url":null,"abstract":"The laws of classical mechanics are rebuilt in the frame of new thermodynamics. Heat is the sum of kinetic energy, system work, and system potential of gas, while force is the linear gradients of heat variation. Exporters and importers of force are evident in terms of exotherm and endotherm. Temperature and volume gradients create asymmetric forces driving rotation and spin (self-rotation). It verifies that force transfer doesn’t need a medium. As an outstanding achievement, a brief and general equation is derived to predict the equilibrium distance of molecular interaction: L_e=∛((3π^(α-1) M_A g)/(4N_A kT)), without using any assumption, such as van der Waals force and dispersion forces. In addition, the origins and attributes of repulsion and attraction are disclosed. Predicting results is applausive. For example, at 298 K, Le for N2, O2, and CH4 are 3.11, 3.11, and 3.68 Å, comparable to the data adopted in MD simulations of the literature. Furthermore, the relationship between electricity and mass is established. An electron is characterized as a particle with a large α dependent on the interaction distance. Two electrons are mutually attractive from a distance depending on temperature. The electromagnetic phenomena are integrated.","PeriodicalId":9813,"journal":{"name":"ChemRxiv","volume":"32 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"From new thermodynamics to classical mechanics\",\"authors\":\"Henmei, Ni\",\"doi\":\"10.26434/chemrxiv-2024-35kds-v4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The laws of classical mechanics are rebuilt in the frame of new thermodynamics. Heat is the sum of kinetic energy, system work, and system potential of gas, while force is the linear gradients of heat variation. Exporters and importers of force are evident in terms of exotherm and endotherm. Temperature and volume gradients create asymmetric forces driving rotation and spin (self-rotation). It verifies that force transfer doesn’t need a medium. As an outstanding achievement, a brief and general equation is derived to predict the equilibrium distance of molecular interaction: L_e=∛((3π^(α-1) M_A g)/(4N_A kT)), without using any assumption, such as van der Waals force and dispersion forces. In addition, the origins and attributes of repulsion and attraction are disclosed. Predicting results is applausive. For example, at 298 K, Le for N2, O2, and CH4 are 3.11, 3.11, and 3.68 Å, comparable to the data adopted in MD simulations of the literature. Furthermore, the relationship between electricity and mass is established. An electron is characterized as a particle with a large α dependent on the interaction distance. Two electrons are mutually attractive from a distance depending on temperature. The electromagnetic phenomena are integrated.\",\"PeriodicalId\":9813,\"journal\":{\"name\":\"ChemRxiv\",\"volume\":\"32 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemRxiv\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.26434/chemrxiv-2024-35kds-v4\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemRxiv","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26434/chemrxiv-2024-35kds-v4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
经典力学定律在新热力学的框架内得以重建。热量是气体的动能、系统功和系统势的总和,而力则是热量变化的线性梯度。力的输出者和输入者在放热和内热方面显而易见。温度梯度和体积梯度产生了驱动旋转和自旋(自转)的非对称力。它验证了力的传递不需要介质。作为一项杰出成就,我们推导出了一个简明的一般方程,用于预测分子相互作用的平衡距离:L_e=∛((3π^(α-1) M_A g)/(4N_A kT)),而无需使用任何假设,如范德华力和分散力。此外,还揭示了斥力和吸引力的起源和属性。预测结果令人称赞。例如,在 298 K 时,N2、O2 和 CH4 的 Le 分别为 3.11、3.11 和 3.68 Å,与文献中 MD 模拟所采用的数据相当。此外,还建立了电量与质量之间的关系。电子的特点是粒子的α很大,取决于相互作用距离。两个电子相互吸引的距离取决于温度。电磁现象是综合的。
The laws of classical mechanics are rebuilt in the frame of new thermodynamics. Heat is the sum of kinetic energy, system work, and system potential of gas, while force is the linear gradients of heat variation. Exporters and importers of force are evident in terms of exotherm and endotherm. Temperature and volume gradients create asymmetric forces driving rotation and spin (self-rotation). It verifies that force transfer doesn’t need a medium. As an outstanding achievement, a brief and general equation is derived to predict the equilibrium distance of molecular interaction: L_e=∛((3π^(α-1) M_A g)/(4N_A kT)), without using any assumption, such as van der Waals force and dispersion forces. In addition, the origins and attributes of repulsion and attraction are disclosed. Predicting results is applausive. For example, at 298 K, Le for N2, O2, and CH4 are 3.11, 3.11, and 3.68 Å, comparable to the data adopted in MD simulations of the literature. Furthermore, the relationship between electricity and mass is established. An electron is characterized as a particle with a large α dependent on the interaction distance. Two electrons are mutually attractive from a distance depending on temperature. The electromagnetic phenomena are integrated.