Development of Mg2TiO4:Mn4+ phosphors for enhanced red LED emission and forensic fingerprint analysis

The advancement in the development of inorganic phosphors marks a significant milestone in the fields of LED technology and forensic science. Herein, MgTiO:Mn (MTO:Mn) novel red-emitting phosphors are synthesized through a solvothermal method, which demonstrates a promising approach for enhancing latent fingerprint detection capabilities and improving the performance of red LEDs. The confirmation of the cubic structure post-annealing and the nano-nature as revealed by TEM analysis underpin the MTO:Mn phosphors suitability for these applications. The broad excitation spectra and the sharp red emission at 659 nm, coupled with the optimal doping concentration, showcase the MTO:Mn phosphor's efficient luminescence properties. Moreover, the calculated critical distance between Mn ions (32.906 Å) elucidates the concentration quenching mechanism, which is pivotal for optimizing the performance. The high purity of the emitted red light (97.2 %) and the precise CIE coordinates (0.5969, 0.2926) of the MTO:Mn phosphor suggest its potential for producing high-quality red LEDs. Additionally, the capability of MTO:Mn phosphors to reveal detailed and high-resolution latent fingerprints offers a more reliable and efficient method for processing and analyzing crucial evidence. These findings not only contribute to the scientific understanding of MTO:Mn phosphor materials but also pave the way for their practical application in cutting-edge technologies.