半导体的分子方法:向生态友好型制造和神经启发界面转变

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Kirill Yu. Monakhov, Christoph Meinecke, Marco Moors, Carolin Schmitz-Antoniak, Thomas Blaudeck, Julia Hann, Christopher Bickmann, Danny Reuter, Thomas Otto, Stefan E. Schulz, Harish Parala, Anjana Devi
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引用次数: 0

摘要

通过物理降级实现更复杂类型的存储器和逻辑器件的能量消耗、超纯水的损耗、晶圆清洗过程中大量(有毒)化学品的消耗,以及标准半导体固态合成和薄膜生长的高热预算(包括稀土元素的使用)--所有这些都对半导体材料科学与技术提出了巨大挑战。因此,研究和开发微纳米制造和化学功能化的替代方法,使新型资源和能源效率高的半导体成为每个计算机芯片的核心部件至关重要。其中一个大有可为的机会是将当今的互补金属氧化物半导体(CMOS)电子器件转变为由分子设计和室温下多级开关机制驱动的环保型神经启发电子器件。在逐步过渡到面向未来的万物互联(IoE)概念的背景下,半导体制造中电子传输和开关材料的可持续化学技术,以及具有新的非常规纳米物理特性、更高性能和增强功能(超越 CMOS 和 More-than-Moore)的器件开发正变得越来越重要。在这篇文章中,我们将重点讨论从单源(分子)前体制备半导体的技术意义,以及利用 DNA 折纸纳米技术和刺激响应型金属氧簇离子(如聚氧金属盐 (POM))实现半导体功能化的前景。我们还介绍了利用软 X 射线对这些合格分子系统进行高级表征的方法。我们强调了使用基于溶液的方法自下而上制备新型和混合半导体的技术相关性,以及其具有挑战性的可扩展性和分子技术方法与基于光刻技术的大规模生产的兼容性。我们的文章旨在为实现联合国可持续发展目标 9(工业、创新和基础设施)做出贡献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Molecular approach to semiconductors: a shift towards ecofriendly manufacturing and neuroinspired interfaces
Energy dissipation through physical downscaling towards more complex types of memory and logic devices, loss of ultrapure water and consumption of large amounts of (toxic) chemicals for wafer cleaning processes, as well as high thermal budget of solid-state synthesis and thin film growth of standard semiconductors including the use of rare earth elements – all this poses great challenges for semiconductor materials science and technology. Therefore, research and development of alternative methods for micro- and nanofabrication and chemical functionalization of a new type of resource- and energy-efficient semiconductors as the core component of every computer chip is crucial. One of the promising opportunities is the transformation of today’s complementary metal-oxide-semiconductor (CMOS) electronics into ecofriendly and neuroinspired electronics driven by molecular design and multi-level switching mechanisms at room temperature. The sustainable chemical technology of electron transport and switching materials in semiconductor manufacturing and the development of devices with new unconventional nanophysics, improved performance, and augmented functionalities (beyond-CMOS and More-than-Moore) is becoming increasingly important in the context of a gradual transition to a future-oriented concept of Internet of Everything (IoE). In this article, we focus on the technological significance of semiconductor preparation from single-source (molecular) precursors and the prospect of functionalizing semiconductors using DNA origami nanotechnology and stimuli-responsive metal–oxygen cluster ions such as polyoxometalates (POMs). We also describe the advanced characterization of these qualified molecular systems by soft X-rays. We emphasize the technical relevance of using solution-based methods for the bottom-up preparation of novel and hybrid semiconductors as well as their challenging scalability and the compatibility of methods of molecular technology with lithography-based mass production. Our article aims to contribute to the achievement of the United Nations’ Sustainable Development Goal 9 (Industry, Innovation and Infrastructure).
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来源期刊
Pure and Applied Chemistry
Pure and Applied Chemistry 化学-化学综合
CiteScore
4.00
自引率
0.00%
发文量
60
审稿时长
3-8 weeks
期刊介绍: Pure and Applied Chemistry is the official monthly Journal of IUPAC, with responsibility for publishing works arising from those international scientific events and projects that are sponsored and undertaken by the Union. The policy is to publish highly topical and credible works at the forefront of all aspects of pure and applied chemistry, and the attendant goal is to promote widespread acceptance of the Journal as an authoritative and indispensable holding in academic and institutional libraries.
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