调节催化氨氧化反应中的 N-H 键裂解

IF 3 4区化学 Q3 CHEMISTRY, PHYSICAL

ChemPhotoChem Pub Date : 2024-09-19 DOI:10.1002/cptc.202400210

Lei Wu, Zhenlin Chen, Yuchao Zhang

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引用次数: 0

摘要

氨氧化反应（AOR）在环境修复和能源利用方面具有巨大潜力。然而，AOR 复杂的反应机理给其应用带来了诸多挑战。要克服这些挑战并实现高效的 AOR 工艺，透彻了解每个基本反应步骤，尤其是 N-H 键的裂解至关重要。本综述深入探讨了 N-H 键裂解对 AOR 反应速率和选择性的影响，并总结了促进这一关键步骤的最新进展。此外，我们还讨论了 N-H 键裂解所面临的挑战，并对高效催化 AOR 系统的设计提出了见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Modulating N−H Bond Cleavage in Catalytic Ammonia Oxidation Reaction

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Modulating N−H Bond Cleavage in Catalytic Ammonia Oxidation Reaction

The ammonia oxidation reaction (AOR) exhibits significant potential for environmental remediation and energy utilization. Nevertheless, the complex reaction mechanism of the AOR poses numerous challenges to its application. To overcome these challenges and realize an efficient AOR process, a thorough understanding of every elementary reaction step, especially the cleavage of N−H bonds, is crucial. This review delves into the influence of N−H bond cleavage on the rate and selectivity of AOR, and summarizes the latest advancements in promoting this crucial step. Furthermore, we discuss the challenges faced by N−H bond cleavage and provide insights into the design of efficient catalytic AOR systems.

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来源期刊

ChemPhotoChem Chemistry-Physical and Theoretical Chemistry

CiteScore

5.80

自引率

5.40%

发文量

165

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