Dmitry Leonidovich Kovalenko, Vy Uong Van, Van Phuc Mac, Thien Vuong Nguyen, Lan Pham Thi, Tuan Anh Nguyen, Vladimir Evgenevich Gaishun, Vasili Vasilievich Vaskevich, Dai Lam Tran
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Effect of graphene on mechanical and anti-corrosion properties of TiO2-SiO2 sol-gel coating
Purpose
This paper aims to explore how graphene can improve the mechanical and anti-corrosion properties of TiO2-SiO2 sol-gel coating. This sol-gel coating has been prepared on aluminum alloy substrate using graphene as both nano-filler and corrosion inhibitor.
Design/methodology/approach
To examine the effect of graphene on mechanical properties of sol-gel coating, the abrasion resistance, adhesion strength and scratch resistance of coating have been evaluated. To reveal the effect of graphene on the anti-corrosion property of coating for aluminum alloy, the electrochemical impedance spectroscopy (EIS) has been conducted in 3.5 Wt.% NaCl medium.
Findings
Scanning electron microscopy images indicate that graphene nanoplatelets (GNPs) have been homogeneously dispersed into the sol-gel coating matrices (at the contents from 0.1 to 0.5 Wt.%). Mechanical tests of coatings indicate that the graphene content of 0.5 Wt.% provides highest values of adhesion strength (1.48 MPa), scratch resistance (850 N) and abrasion strength (812 L./mil.) for the sol-gel coating. The EIS data show that the higher content of GNPs improve both R1 (coating) and R2 (coating/Al interface) resistances. In addition to enhancing the coating barrier performance (graphene acts as nanofiller/nano-reinforcer for coating matrix), other mechanism can be at work to account for the role of the graphene inhibitor in improving the anticorrosive performance at the coating/Al interface.
Originality/value
Application of graphene-based sol-gel coating for protection of aluminum and its alloy is very promising.
期刊介绍：
Anti-Corrosion Methods and Materials publishes a broad coverage of the materials and techniques employed in corrosion prevention. Coverage is essentially of a practical nature and designed to be of material benefit to those working in the field. Proven applications are covered together with company news and new product information. Anti-Corrosion Methods and Materials now also includes research articles that reflect the most interesting and strategically important research and development activities from around the world.
Every year, industry pays a massive and rising cost for its corrosion problems. Research and development into new materials, processes and initiatives to combat this loss is increasing, and new findings are constantly coming to light which can help to beat corrosion problems throughout industry. This journal uniquely focuses on these exciting developments to make essential reading for anyone aiming to regain profits lost through corrosion difficulties.
• New methods, materials and software
• New developments in research and industry
• Stainless steels
• Protection of structural steelwork
• Industry update, conference news, dates and events
• Environmental issues
• Health & safety, including EC regulations
• Corrosion monitoring and plant health assessment
• The latest equipment and processes
• Corrosion cost and corrosion risk management.
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