Diffusion-limited settling of highly porous particles in density-stratified fluids

The vertical transport of solid material in a stratified medium is fundamental to a number of environmental applications, with implications for the carbon cycle and nutrient transport in marine ecosystems. In this work, we study the diffusion-limited settling of highly porous particles in a density-stratified fluid through a combination of experiment, analysis, and numerical simulation. By delineating and appealing to the diffusion-limited regime wherein buoyancy effects due to mass adaptation dominate hydrodynamic drag, we derive a simple expression for the steady settling velocity of a sphere as a function of the density, size, and diffusivity of the solid, as well as the density gradient of the background fluid. In this regime, smaller particles settle faster, in contrast with most conventional hydrodynamic drag mechanisms. Furthermore, we outline a general mathematical framework for computing the steady settling speed of a body of arbitrary shape in this regime and compute exact results for the case of general ellipsoids. Using hydrogels as a highly porous model system, we validate the predictions with laboratory experiments in linear stratification for a wide range of parameters. Lastly, we show how the predictions can be applied to arbitrary slowly varying background density profiles and demonstrate how a measured particle position over time can be used to reconstruct the background density profile.