基于 TiO2 /Au-NPs 敏化技术的光纤表面等离子体共振传感器

Hua-Long Du, Nuerguli Kari, Ben Li, Qi Wang
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摘要

基于二氧化钛(TiO)和金纳米粒子(Au-NPs)敏化的光纤表面等离子体共振(SPR)传感器是提高灵敏度和优点系数(FOM)的一种实用手段。通过有限元模拟和实验测试发现,在具有高介电常数和高介电导率的 TiO 中,载流子运动速度快、消耗少,从而增强了光电流信号并导致电荷再分布,进而增强了电场;而 Au-NPs 会激发更强的局域表面等离子体共振(LSPR)现象,二者发生电场共振耦合。这种传感器的灵敏度更高,因为其表面电场比传统的金薄膜传感器强 3.67 倍。当暴露在外部条件下时,在折射率(RI)为 1.33213-1.34055 的范围内,灵敏度可达 9715 nm/RIU,是传统金膜传感器的 4.69 倍。FOM 可达到 57.8 RIU,是传统金膜传感器的 2.05 倍。此外,传感器表面的 TiO 和 Au-NPs 不易塌陷,稳定性测试结果表明,相对标准偏差(RSD)为 0.5929 %,表现出良好的可靠性和稳定性。该传感器结构非常简单,比较容易制作,在生化检测领域具有良好的适用性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The fiber surface plasmon resonance sensor based on TiO2 /Au-NPs sensitization
The fiber Surface plasmon resonance (SPR) sensor based on titanium dioxide(TiO) and Au nanoparticles (Au-NPs) sensitization is offered as a practical means of increasing the sensitivity and figure of merit (FOM). Through finite element simulation and experimental testing, it is found that in TiO with high dielectric constant and high dielectric conductivity, the carrier movement is fast and consumption is low, which enhances the photocurrent signal and leads to charge redistribution, thus enhances the electric field; while the Au-NPs will stimulate the stronger Localized Surface plasmon resonance (LSPR) phenomenon, and both of them will undergo electric field resonance coupling. The sensitivity of the sensor is higher because its surface electric field is 3.67 times stronger than the conventional Au film sensor. When exposed to external conditions, the sensitivity can reach 9715 nm/RIU within the refractive index (RI) at 1.33213–1.34055, which is 4.69 times higher than a conventional Au film sensor. The FOM can reach 57.8 RIU, which is 2.05 times higher than the conventional Au film sensor. In addition, TiO and Au-NPs on the surface of the sensor are less prone to collapse, and the stability test results show that the relative standard deviation (RSD) is 0.5929 %, which exhibits good reliability and stability. The structure of the sensor is very simple, relatively easy to fabricate, and has good applicability in the field of biochemical testing.
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