{"title":"铬镍基有机框架对有效电化学测定环境样品中氟胺的协同效应","authors":"Navaneeth Kumar Ravikumar, Panneerselvam Perumal","doi":"10.1557/s43578-024-01421-6","DOIUrl":null,"url":null,"abstract":"<p>An innovative electrochemical sensor has been developed using Cr–Ni bimetal-organic frameworks (MOFs) for detecting the anti-prostate cancer medication, flutamide, in environmental samples. The sensor utilizes a modified glassy carbon electrode (GCE). The Cr–Ni MOF-modified electrode demonstrated significantly higher peak currents compared to the bare GCE or electrodes modified with either Cr-MOF or Ni-MOF alone. This enhanced performance is attributed to superior conductivity, robust catalytic capabilities, and the synergistic interactions of bimetals within the organic framework assembly. The sensor was optimized for flutamide detection using differential pulse voltammetry in a phosphate buffer solution at pH 9. It achieved a linear detection range of 10 to 100 μM, a low detection limit (LOD) of 0.09 μM, and a limit of quantification (LOQ) of 0.30 μM. The sensor also demonstrated high stability, specificity, and reproducibility.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\n","PeriodicalId":16306,"journal":{"name":"Journal of Materials Research","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic effect of chromium–nickel based organic frameworks toward an effective electrochemical determination of flutamide in environmental samples\",\"authors\":\"Navaneeth Kumar Ravikumar, Panneerselvam Perumal\",\"doi\":\"10.1557/s43578-024-01421-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>An innovative electrochemical sensor has been developed using Cr–Ni bimetal-organic frameworks (MOFs) for detecting the anti-prostate cancer medication, flutamide, in environmental samples. The sensor utilizes a modified glassy carbon electrode (GCE). The Cr–Ni MOF-modified electrode demonstrated significantly higher peak currents compared to the bare GCE or electrodes modified with either Cr-MOF or Ni-MOF alone. This enhanced performance is attributed to superior conductivity, robust catalytic capabilities, and the synergistic interactions of bimetals within the organic framework assembly. The sensor was optimized for flutamide detection using differential pulse voltammetry in a phosphate buffer solution at pH 9. It achieved a linear detection range of 10 to 100 μM, a low detection limit (LOD) of 0.09 μM, and a limit of quantification (LOQ) of 0.30 μM. The sensor also demonstrated high stability, specificity, and reproducibility.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical Abstract</h3>\\n\",\"PeriodicalId\":16306,\"journal\":{\"name\":\"Journal of Materials Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-09-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1557/s43578-024-01421-6\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1557/s43578-024-01421-6","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Synergistic effect of chromium–nickel based organic frameworks toward an effective electrochemical determination of flutamide in environmental samples
An innovative electrochemical sensor has been developed using Cr–Ni bimetal-organic frameworks (MOFs) for detecting the anti-prostate cancer medication, flutamide, in environmental samples. The sensor utilizes a modified glassy carbon electrode (GCE). The Cr–Ni MOF-modified electrode demonstrated significantly higher peak currents compared to the bare GCE or electrodes modified with either Cr-MOF or Ni-MOF alone. This enhanced performance is attributed to superior conductivity, robust catalytic capabilities, and the synergistic interactions of bimetals within the organic framework assembly. The sensor was optimized for flutamide detection using differential pulse voltammetry in a phosphate buffer solution at pH 9. It achieved a linear detection range of 10 to 100 μM, a low detection limit (LOD) of 0.09 μM, and a limit of quantification (LOQ) of 0.30 μM. The sensor also demonstrated high stability, specificity, and reproducibility.
期刊介绍：
Journal of Materials Research (JMR) publishes the latest advances about the creation of new materials and materials with novel functionalities, fundamental understanding of processes that control the response of materials, and development of materials with significant performance improvements relative to state of the art materials. JMR welcomes papers that highlight novel processing techniques, the application and development of new analytical tools, and interpretation of fundamental materials science to achieve enhanced materials properties and uses. Materials research papers in the following topical areas are welcome.
• Novel materials discovery
• Electronic, photonic and magnetic materials
• Energy Conversion and storage materials
• New thermal and structural materials
• Soft materials
• Biomaterials and related topics
• Nanoscale science and technology
• Advances in materials characterization methods and techniques
• Computational materials science, modeling and theory
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