过渡金属催化 C-H 键官能化 C-糖苷的新进展

IF 1.7 3区 化学 Q3 CHEMISTRY, ORGANIC
Zanjila Azeem, Sunny Maurya, Mohammad Ovais, Rekha Sagwan, Atul Dubey, Pintu Kumar Mandal
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引用次数: 0

摘要

:本综述总结了过渡金属催化的 C-H 键官能化方法在获得 C-支链(杂)芳基/烯基/烷基糖苷方面的最新趋势、反应特点和拟议机制。最近,过渡金属催化的 C-H 键官能化已成为一种开创性的多功能方法,可用于可行、高效地生产强效 C-支链苷类化合物。如今,由于 C-H 键错综复杂且高度稳定的性质,碳水化合物化学中对 C-H 键的位点选择性官能化要求很高。在此背景下,我们系统地总结了炔类化合物的 C-H 糖基化、糖苷的 C-H 芳基化和 Cattelani-strategy 的机理研究。此外,我们还讨论了过渡金属催化的 C-糖基化在形成生物活性分子方面的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Emerging Advances in Transition Metal-Catalyzed C-H Bond Functionalizations Towards C-Glycosides
: This review summarizes the recent trends in the transition-metal-catalyzed C-H bond functionalization approach to access C-branched (hetero)aryl/alkenyl/alkyl glycosides with reaction characteristics and proposed mechanisms. Recently, the Transition-metal-catalyzed C-H functionalization has arisen as a groundbreaking and versatile method for producing potent C-branched glycosides feasibly and efficiently. Nowadays, site-selective functionalization of C-H bonds in carbohydrate chemistry is highly demanded, owing to the intricate and highly stable nature of C-H bonds. In this context, we systematically summarize the C-H glycosylation of arenes, C-H arylation of glycoside, and Cattelani-strategy with mechanistic investigation. Also, the applications of transition-metal-catalyzed C-glycosylation for the formation of biologically active molecules are discussed.
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来源期刊
Current Organic Chemistry
Current Organic Chemistry 化学-有机化学
CiteScore
3.70
自引率
7.70%
发文量
76
审稿时长
1 months
期刊介绍: Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.
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