Subhojit Pal, Barry W. Ninham, John F. Dobson, Mathias Boström
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引用次数: 0
摘要
我们考虑了 N 个平行长物体(如 DNA/RNA 链或金属纳米管)之间的色散(范德华,vdW)相互作用,这些物体主要沿长轴具有极性。在一个准一维模型中,我们证明了不可还原的 N 个物体 vdW 能量贡献对偶数 N 为负(吸引力),对奇数 N 为正(排斥力)。这表明在纳米科学和生物学中,拉长结构更倾向于偶数 N 聚类。这项工作可能会对纳米管束的形成以及长链生物分子在超过化学键长度的间隔内的聚类等方面产生影响。
Attractive and repulsive terms in multi-object dispersion interactions
We consider the dispersion (van der Waals, vdW) interaction among N parallel
elongated objects such as DNA/RNA strands or metallic nanotubes, which are
polarizable primarily along the long axis. Within a quasi-one-dimensional
model, we prove that the irreducible N -object vdW energy contribution is
negative (attractive) for even N and positive (repulsive) for odd N. We confirm
these results up to $N=4$ via a 3-dimensional plasma cylinder model. This
suggests a preference for even-N clustering of elongated structures in
nanoscience and biology. This work could have implications e.g. for nanotube
bundle formation and for the clustering of long-chain biomolecules at
separations exceeding chemical bond lengths.