多物体色散相互作用中的吸引项和排斥项

Subhojit Pal, Barry W. Ninham, John F. Dobson, Mathias Boström
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引用次数: 0

摘要

我们考虑了 N 个平行长物体(如 DNA/RNA 链或金属纳米管)之间的色散(范德华,vdW)相互作用,这些物体主要沿长轴具有极性。在一个准一维模型中,我们证明了不可还原的 N 个物体 vdW 能量贡献对偶数 N 为负(吸引力),对奇数 N 为正(排斥力)。这表明在纳米科学和生物学中,拉长结构更倾向于偶数 N 聚类。这项工作可能会对纳米管束的形成以及长链生物分子在超过化学键长度的间隔内的聚类等方面产生影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Attractive and repulsive terms in multi-object dispersion interactions
We consider the dispersion (van der Waals, vdW) interaction among N parallel elongated objects such as DNA/RNA strands or metallic nanotubes, which are polarizable primarily along the long axis. Within a quasi-one-dimensional model, we prove that the irreducible N -object vdW energy contribution is negative (attractive) for even N and positive (repulsive) for odd N. We confirm these results up to $N=4$ via a 3-dimensional plasma cylinder model. This suggests a preference for even-N clustering of elongated structures in nanoscience and biology. This work could have implications e.g. for nanotube bundle formation and for the clustering of long-chain biomolecules at separations exceeding chemical bond lengths.
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