聚氧化金属酸盐衍生材料作为模仿漆酶的纳米酶和对硝基苯酚水污染修复还原催化剂

IF 2.6 4区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ChemNanoMat Pub Date : 2024-09-08 DOI:10.1002/cnma.202400336
Ping Sun, Xinxin Xu, Jin Chen
{"title":"聚氧化金属酸盐衍生材料作为模仿漆酶的纳米酶和对硝基苯酚水污染修复还原催化剂","authors":"Ping Sun,&nbsp;Xinxin Xu,&nbsp;Jin Chen","doi":"10.1002/cnma.202400336","DOIUrl":null,"url":null,"abstract":"<p>p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, <b>PV<sub>14</sub>@MIL-88A</b>, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na<sub>7</sub>H<sub>2</sub>[PV<sub>14</sub>O<sub>42</sub>] (PV<sub>14</sub>) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of <b>PV<sub>14</sub>@MIL-88A</b> is derived from the optimized d-band center in PV<sub>14</sub>. Upon calcination with dicyandiamide (DCDA), <b>PV<sub>14</sub>@MIL-88A</b> transforms into <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b>. In the presence of NaBH<sub>4</sub>, <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe<sub>2</sub>O<sub>3</sub> and VO<sub>2</sub> in <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> enhances adsorption and subsequent reduction of PNP. The saturation magnetization of <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> reaches 25 emu g<sup>−1</sup>, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 1","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polyoxometalate Derived Materials as Laccase-Mimic Nanozyme and Reduction Catalyst for p-Nitrophenol Remediation in Water\",\"authors\":\"Ping Sun,&nbsp;Xinxin Xu,&nbsp;Jin Chen\",\"doi\":\"10.1002/cnma.202400336\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, <b>PV<sub>14</sub>@MIL-88A</b>, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na<sub>7</sub>H<sub>2</sub>[PV<sub>14</sub>O<sub>42</sub>] (PV<sub>14</sub>) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of <b>PV<sub>14</sub>@MIL-88A</b> is derived from the optimized d-band center in PV<sub>14</sub>. Upon calcination with dicyandiamide (DCDA), <b>PV<sub>14</sub>@MIL-88A</b> transforms into <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b>. In the presence of NaBH<sub>4</sub>, <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe<sub>2</sub>O<sub>3</sub> and VO<sub>2</sub> in <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> enhances adsorption and subsequent reduction of PNP. The saturation magnetization of <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> reaches 25 emu g<sup>−1</sup>, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.</p>\",\"PeriodicalId\":54339,\"journal\":{\"name\":\"ChemNanoMat\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemNanoMat\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400336\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400336","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

对硝基苯酚(PNP)是一种剧毒水污染物,对人类健康和环境构成重大风险。利用模仿漆酶活性的纳米酶比色法检测 PNP 是一种可行的方法。在本研究中,通过将 Na7H2[PV14O42] (PV14) 加入金属有机框架 (MOF) MIL-88A 中,合成了具有卓越漆酶模拟能力的 PV14@MIL-88A。这种纳米酶具有最佳的裂解酶模拟活性,可通过智能手机的比色法和数字图像比色法有效检测 PNP。理论分析表明,PV14@MIL-88A 杰出的长效酶模拟活性源自 PV14 中优化的 d 波段中心。用双氰胺(DCDA)煅烧后,PV14@MIL-88A 转化为 Fe2O3/VO2@NCNF。在 NaBH4 的存在下,Fe2O3/VO2@NCNF 可促进 PNP 向对氨基苯酚(PAP)的转化,对氨基苯酚是对乙酰氨基酚合成过程中必不可少的前体。Fe2O3/VO2@NCNF 中的 Fe2O3 和 VO2 之间的相互作用增强了对 PNP 的吸附和随后的还原。Fe2O3/VO2@NCNF 的饱和磁化率达到 25 emu-g-1,这为还原过程中的高效磁分离提供了支持。这项研究不仅推进了一种检测 PNP 的有效方法,还促进了 PNP 从一种有害污染物转变为一种有价值的化学前体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Polyoxometalate Derived Materials as Laccase-Mimic Nanozyme and Reduction Catalyst for p-Nitrophenol Remediation in Water

Polyoxometalate Derived Materials as Laccase-Mimic Nanozyme and Reduction Catalyst for p-Nitrophenol Remediation in Water

p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, PV14@MIL-88A, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na7H2[PV14O42] (PV14) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of PV14@MIL-88A is derived from the optimized d-band center in PV14. Upon calcination with dicyandiamide (DCDA), PV14@MIL-88A transforms into Fe2O3/VO2@NCNF. In the presence of NaBH4, Fe2O3/VO2@NCNF facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe2O3 and VO2 in Fe2O3/VO2@NCNF enhances adsorption and subsequent reduction of PNP. The saturation magnetization of Fe2O3/VO2@NCNF reaches 25 emu g−1, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemNanoMat
ChemNanoMat Energy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍: ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信