{"title":"聚氧化金属酸盐衍生材料作为模仿漆酶的纳米酶和对硝基苯酚水污染修复还原催化剂","authors":"Ping Sun, Xinxin Xu, Jin Chen","doi":"10.1002/cnma.202400336","DOIUrl":null,"url":null,"abstract":"<p>p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, <b>PV<sub>14</sub>@MIL-88A</b>, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na<sub>7</sub>H<sub>2</sub>[PV<sub>14</sub>O<sub>42</sub>] (PV<sub>14</sub>) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of <b>PV<sub>14</sub>@MIL-88A</b> is derived from the optimized d-band center in PV<sub>14</sub>. Upon calcination with dicyandiamide (DCDA), <b>PV<sub>14</sub>@MIL-88A</b> transforms into <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b>. In the presence of NaBH<sub>4</sub>, <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe<sub>2</sub>O<sub>3</sub> and VO<sub>2</sub> in <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> enhances adsorption and subsequent reduction of PNP. The saturation magnetization of <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> reaches 25 emu g<sup>−1</sup>, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 1","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polyoxometalate Derived Materials as Laccase-Mimic Nanozyme and Reduction Catalyst for p-Nitrophenol Remediation in Water\",\"authors\":\"Ping Sun, Xinxin Xu, Jin Chen\",\"doi\":\"10.1002/cnma.202400336\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, <b>PV<sub>14</sub>@MIL-88A</b>, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na<sub>7</sub>H<sub>2</sub>[PV<sub>14</sub>O<sub>42</sub>] (PV<sub>14</sub>) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of <b>PV<sub>14</sub>@MIL-88A</b> is derived from the optimized d-band center in PV<sub>14</sub>. Upon calcination with dicyandiamide (DCDA), <b>PV<sub>14</sub>@MIL-88A</b> transforms into <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b>. In the presence of NaBH<sub>4</sub>, <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe<sub>2</sub>O<sub>3</sub> and VO<sub>2</sub> in <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> enhances adsorption and subsequent reduction of PNP. The saturation magnetization of <b>Fe<sub>2</sub>O<sub>3</sub>/VO<sub>2</sub>@NCNF</b> reaches 25 emu g<sup>−1</sup>, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.</p>\",\"PeriodicalId\":54339,\"journal\":{\"name\":\"ChemNanoMat\",\"volume\":\"11 1\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemNanoMat\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400336\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400336","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Polyoxometalate Derived Materials as Laccase-Mimic Nanozyme and Reduction Catalyst for p-Nitrophenol Remediation in Water
p-Nitrophenol (PNP), a highly toxic water pollutant, poses significant risks to human health and the environment. For detecting PNP, a colorimetric method utilizing a nanozyme that mimics laccase activity presents a viable approach. In this study, PV14@MIL-88A, a robust nanozyme with superior laccase-mimic capabilities, was synthesized by incorporating Na7H2[PV14O42] (PV14) into MIL-88A, a metal-organic framework (MOF). This nanozyme demonstrates optimal laccase-mimicking activity, enabling effective PNP detection via colorimetry and digital image colorimetry using smartphones. Theoretical analyses suggest that the outstanding laccase-mimic activity of PV14@MIL-88A is derived from the optimized d-band center in PV14. Upon calcination with dicyandiamide (DCDA), PV14@MIL-88A transforms into Fe2O3/VO2@NCNF. In the presence of NaBH4, Fe2O3/VO2@NCNF facilitates the conversion of PNP to p-aminophenol (PAP), an essential precursor in paracetamol synthesis. The interaction between Fe2O3 and VO2 in Fe2O3/VO2@NCNF enhances adsorption and subsequent reduction of PNP. The saturation magnetization of Fe2O3/VO2@NCNF reaches 25 emu g−1, which supports efficient magnetic separation in the reduction process. This study not only advances an effective method for PNP detection but also facilitates its transformation from a hazardous pollutant into a valuable chemical precursor.
ChemNanoMatEnergy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍:
ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.