You-Hui Tang, Peng Chen, Jin Yin, Jianghuan Shi, Yi-Jun Jiang
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Solvent-Controlled Divergent Synthesis of Thiocyanated Carbazoles and Di/Triphenylamines
A solvent-controlled divergent thiocyanation of carbazoles and di/triphenylamines has been developed. Using either CH3CN/H2O (3:1) or DMSO as the solvent, a facile and efficient protocol for the solvent-controlled divergent synthesis of mono- and di-thiocyanation of carbazoles and di/triphenylamines was achieved. The salient features of this transformation include simple and mild reaction conditions, easily available substrates, and broad substrate scope.
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