银(钯)双金属纳米粒子的合成与催化特性

IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
L. I. Bazylyak, R. B. Sheperovych, P. Ya. Liutyy, M. V. Shepida, O. I. Kuntyi, A. R. Kytsya
{"title":"银(钯)双金属纳米粒子的合成与催化特性","authors":"L. I. Bazylyak, R. B. Sheperovych, P. Ya. Liutyy, M. V. Shepida, O. I. Kuntyi, A. R. Kytsya","doi":"10.1007/s11003-024-00840-4","DOIUrl":null,"url":null,"abstract":"<p>Ag(Pd) bimetallic nanostructures (Ag(Pd)NPs) were synthesized using the galvanic replacement of palladium ions with silver nanoparticles. Based on a comparative analysis of the results of scanning electron microscopy, energy dispersive X-ray microanalysis, and X-ray powder diffraction, it was established that the obtained Ag(Pd)NPs can be considered as “core-shell” nanosystems, in which the core is silver, and the shells are palladium nanoparticles with a size of 5–15 nm. Ag(Pd)NPs were studied as catalysts for the aerobic liquid-phase oxidation of benzyl alcohol. The addition of Ag(Pd)NPs to the reaction system accelerates the reaction in 14 times.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"8 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Catalytic Properties of Ag(Pd) Bimetallic Nanoparticles\",\"authors\":\"L. I. Bazylyak, R. B. Sheperovych, P. Ya. Liutyy, M. V. Shepida, O. I. Kuntyi, A. R. Kytsya\",\"doi\":\"10.1007/s11003-024-00840-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Ag(Pd) bimetallic nanostructures (Ag(Pd)NPs) were synthesized using the galvanic replacement of palladium ions with silver nanoparticles. Based on a comparative analysis of the results of scanning electron microscopy, energy dispersive X-ray microanalysis, and X-ray powder diffraction, it was established that the obtained Ag(Pd)NPs can be considered as “core-shell” nanosystems, in which the core is silver, and the shells are palladium nanoparticles with a size of 5–15 nm. Ag(Pd)NPs were studied as catalysts for the aerobic liquid-phase oxidation of benzyl alcohol. The addition of Ag(Pd)NPs to the reaction system accelerates the reaction in 14 times.</p>\",\"PeriodicalId\":18230,\"journal\":{\"name\":\"Materials Science\",\"volume\":\"8 1\",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-08-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11003-024-00840-4\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11003-024-00840-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

利用银纳米粒子电化学置换钯离子的方法合成了Ag(Pd)双金属纳米结构(Ag(Pd)NPs)。根据对扫描电子显微镜、能量色散 X 射线显微分析和 X 射线粉末衍射结果的比较分析,确定所获得的 Ag(Pd)NPs 可视为 "核壳 "纳米系统,其中核为银,壳为尺寸为 5-15 纳米的钯纳米粒子。研究将 Ag(Pd)NPs 作为催化剂用于苯甲醇的有氧液相氧化。在反应体系中加入 Ag(Pd)NPs 可使反应速度加快 14 倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and Catalytic Properties of Ag(Pd) Bimetallic Nanoparticles

Synthesis and Catalytic Properties of Ag(Pd) Bimetallic Nanoparticles

Ag(Pd) bimetallic nanostructures (Ag(Pd)NPs) were synthesized using the galvanic replacement of palladium ions with silver nanoparticles. Based on a comparative analysis of the results of scanning electron microscopy, energy dispersive X-ray microanalysis, and X-ray powder diffraction, it was established that the obtained Ag(Pd)NPs can be considered as “core-shell” nanosystems, in which the core is silver, and the shells are palladium nanoparticles with a size of 5–15 nm. Ag(Pd)NPs were studied as catalysts for the aerobic liquid-phase oxidation of benzyl alcohol. The addition of Ag(Pd)NPs to the reaction system accelerates the reaction in 14 times.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Materials Science
Materials Science 工程技术-材料科学:综合
CiteScore
1.60
自引率
44.40%
发文量
63
审稿时长
4-8 weeks
期刊介绍: Materials Science reports on current research into such problems as cracking, fatigue and fracture, especially in active environments as well as corrosion and anticorrosion protection of structural metallic and polymer materials, and the development of new materials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信