使用掺铜无定形氧化锆进行芳基硼酸的有氧均偶联反应：催化剂无定形性对反应效率的影响

IF 4.4 3区化学 Q2 CHEMISTRY, PHYSICAL

Catalysis Science & Technology Pub Date : 2024-09-30 DOI:10.1039/d4cy00694a

引用次数: 0

摘要

由于存在易还原的[CuO4]团簇，CuO/am-ZrO2 可在空气和温和条件下促进硼酸的均偶联反应，而无需外部添加剂。这种催化剂抑制了 MeOH 溶剂的吸附，从而减少了与 MeOH 有关的副反应，提高了所需反应的选择性和效率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Aerobic homocoupling of arylboronic acids using Cu-doped amorphous zirconia: impact of catalyst amorphousness on reaction efficiency†

查看原文本刊更多论文

Aerobic homocoupling of arylboronic acids using Cu-doped amorphous zirconia: impact of catalyst amorphousness on reaction efficiency†

CuO/am-ZrO₂ promotes the homocoupling of boronic acids under air and mild conditions without requiring external additives owing to the presence of easily reducible [CuO₄] clusters. This catalyst suppresses the adsorption of MeOH solvent, thereby reducing MeOH-related side reactions and enhancing the selectivity and efficiency of the desired reaction.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Catalysis Science & Technology CHEMISTRY, PHYSICAL-

CiteScore

8.70

自引率

6.00%

发文量

587

审稿时长

1.5 months

期刊介绍： A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days